This law states that the entropy of a pure crystalline substance is zero at the absolute zero of temperature, 0 K
Entropy at Absolute Zero
According to third law of thermodynamics:
The entropy of a system approaches a constant value as the temperature approaches absolute zero.
Based on empirical evidence, this law states that the entropy of a pure crystalline substance is zero at the absolute zero of temperature, 0 K and that it is impossible by means of any process, no matter how idealized, to reduce the temperature of a system to absolute zero in a finite number of steps. This allows us to define a zero point for the thermal energy of a body.
Absolute zero is the coldest theoretical temperature, at which the thermal motion of atoms and molecules reaches its minimum. This is a state at which the enthalpy and entropy of a cooled ideal gas reaches its minimum value, taken as 0. Classically, this would be a state of motionlessness, but quantum uncertainty dictates that the particles still possess a finite zero-point energy. Absolute zero is denoted as 0 K on the Kelvin scale, −273.15 °C on the Celsius scale, and −459.67 °F on the Fahrenheit scale.
References:
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