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Butyraldehyde

Explore the properties, production, uses, and safety measures of Butyraldehyde, a key compound in the chemical industry.

Introduction to Butyraldehyde

Butyraldehyde, commonly known as butanal, is an organic compound that belongs to the aldehyde family. It is a colorless liquid with a pungent, acrid, and fruity smell that is mainly recognized as the scent of fresh apples. Its chemical formula is C4H8O or CH3CH2CH2CHO, signifying a chain of four carbon atoms with an aldehyde group (-CHO) at one end.

Physical and Chemical Properties

With a molar mass of approximately 72.11 g/mol, butyraldehyde is lighter than water, in which it is moderately soluble. It has a boiling point of 75.7 degrees Celsius and a melting point of -90 degrees Celsius. The density of butyraldehyde at room temperature is around 0.81 g/mL, which makes it less dense than water. Its refractive index is measured at approximately 1.377.

  • Chemical Formula: C4H8O or CH3CH2CH2CHO
  • Molar Mass: 72.11 g/mol
  • Density: 0.81 g/mL at 20°C
  • Boiling Point: 75.7°C
  • Melting Point: -90°C
  • Solubility: Moderately soluble in water

Production and Synthesis

The primary commercial method for producing butyraldehyde is through the hydroformylation of propene, commonly known as the Oxo Process. In this process, propene (propylene), carbon monoxide, and hydrogen are combined in the presence of a catalyst to yield butyraldehyde.

The reaction can be summarized as follows:

  1. CH3CH=CH2 + CO + H2 → CH3CH2CH2CHO

Uses and Applications

Butyraldehyde has a wide array of uses in various industries, most notably in the production of other chemicals. It is a precursor to a multitude of compounds, each with their own unique applications. For instance, butyraldehyde is used in the synthesis of 2-ethylhexanol, a key component in the production of plasticizers, and n-butanol, which finds its way into resins, coatings, and plasticizers.

Health Effects and Safety Measures

As with any chemical, exposure to butyraldehyde poses certain health risks. It may cause irritation to the eyes, skin, and respiratory system. Chronic or excessive exposure could potentially lead to more severe health effects. Therefore, it is imperative to handle butyraldehyde with appropriate care and safety measures.

Exposure Routes and First Aid Measures

There are multiple routes through which one can be exposed to butyraldehyde – inhalation, ingestion, and skin or eye contact. It is always recommended to use personal protective equipment (PPE) such as gloves, protective clothing, and eye protection when handling butyraldehyde to prevent accidental exposure.

In case of exposure, the following first aid measures are recommended:

  • Inhalation: The affected individual should be moved to fresh air immediately. If breathing is difficult, administer oxygen and seek medical attention.
  • Ingestion: Do not induce vomiting. If the victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
  • Skin Contact: Wash the affected area with soap and plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation persists.
  • Eye Contact: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek medical aid.

Environmental Impact

While butyraldehyde is readily biodegradable and unlikely to persist in the environment, it is not without environmental impact. It can be toxic to aquatic organisms, leading to potential long-term adverse effects in aquatic environments. Consequently, it should not be released into the environment, and all disposal activities should adhere to local, state, or national regulations.

Conclusion

Butyraldehyde is a versatile organic compound with a multitude of uses in various industries, making it an integral part of our daily lives. Its importance in the chemical industry, particularly in the production of several essential compounds, cannot be overstated. Despite its utility, it’s important to handle butyraldehyde with care due to its potential health and environmental impacts. Understanding its properties, uses, and the precautions required in its handling can ensure its safe and beneficial use.