Control rods are an important safety system of nuclear reactors. Their prompt action and prompt response of the reactor is indispencable. Control rods are used for maintaining the desired state of fission reactions within a nuclear reactor (i.e. subcritical state, critical state, power changes) They constitute a key component of an emergency shutdown system (SCRAM).
Control rods are rods, plates, or tubes containing a neutron absorbing material (material with high absorbtion cross-section for thermal neutron) such as boron, hafnium, cadmium, etc., used to control the power of a nuclear reactor. By absorbing neutrons, a control rod prevents the neutrons from causing further fissions.
Control rods usually constitute cluster control rod assemblies (PWR) and are inserted into guide thimbles within a nuclear fuel assembly. The absorbing material (e.g. pellets of Boron Carbide or Ag-In-Cd alloy) is protected by the cladding usually made of stainless steel.
Neverthless, the melting point of Ag-In-Cd alloy (~790 ̊C), the eutectic temperature of boron carbide (B4C) and Fe (~1150 ̊C) and the eutectic temperature of Fe and Zr (~950 ̊C) are lower than the temperature (≳1 200) at which Zr-alloy fuel cladding begins to be intensively oxidised under severe accident conditions. Accordingly, it is possible that the control rods melt and collapse before the reactor core is significantly damaged in the case of severe accidents.
The following inherent characteristics are required in accident tolerant control rods:
- The reactivity worth of ATCR should be comparable to or exceed that of conventional CR.
- The neutron-absorbing materials used in ATCR should have sufficiently high melting point and high eutectic temperature with cladding to prevent breakage of the CRs prior to extensive fuel rod failure in a severe accident, thus avoiding uncontrollable recriticality even if unborated water is injected for emergency cooling of the core.
The main idea is to replace the conventional neutron-absorbing materials with proper ceramic materials that satisfy the above requirements. The candidate of a new absorber material for ATC includes gadolinia (Gd2O3), samaria (Sm2O3), europia (Eu2O3), dysprosia (Dy2O3), hafnia (HfO2). The melting point of these materials and the liquefaction temperature with Fe are higher than the rapid zirconium alloy oxidation temperature.
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