Rutherford Model of the Atom
The Rutherford model of the atom is a model of the atom devised by the British physicist Ernest Rutherford. Rutherford’s new model for the atom is based on the experimental results, which were obtained from Geiger-Marsden experiments (also called the Rutherford gold foil experiment). The Geiger–Marsden experiments were performed between 1908 and 1913 by Hans Geiger (of Geiger counter fame) and Ernest Marsden (a 20-year-old student who had not yet earned his bachelor’s degree) under the direction of Ernest Rutherford.
Rutherford’s idea was to direct energetic alpha particles at a thin metal foil and measure how an alpha particle beam is scattered when it strikes a thin metal foil. A narrow collimated beam of alpha particles was aimed at a gold foil of approximately 1 μm thickness (about 10,000 atoms thick). Alpha particles are energetic nuclei of helium (usually about 6 MeV). Alpha particles, which are about 7300 times more massive than electrons, have a positive charge of +2e. Because of their relatively much greater mass, alpha particles are not significantly deflected from their paths by the electrons in the metal’s atoms.
According to Thomson’s model, if an alpha particle were to collide with an plum-pudding atom, it would just fly straight through, its path being deflected by at most a fraction of a degree. But in the experiment Geiger and Marsden saw that most of the particles are scattered through rather small angles, but, and this was the big surprise, a very small fraction of them are scattered through very large angles, approaching 180° (i.e., they were recoiled backwards).
In Rutherford’s words:
“It is almost as incredible as if you had fired a fifteen inch shell at a sheet of tissue paper and it came back and hit you.”
Rutherford assumed that, to deflect the alpha particle backward, there must be a very large force. This force could be provided only result from a collision with a massive target or from an interaction with an electric or magnetic field of great strength. In previous experiments, it was shown the deflections had to be electrical or perhaps possibly magnetic in origin.
As a result, Rutherford abandoned the Thomson model. Geiger-Marsden experiments were a landmark series of experiments by which scientists discovered that every atom contains a nucleus (whose diameter is of the order 10-14m.) where all of its positive charge and most of its mass are concentrated in a small region called an atomic nucleus. In Rutherford’s atom, the diameter of its sphere (about 10-10 m) of influence is determined by its electrons. In other words, the nucleus occupies only about 10-12 of the total volume of the atom or less (the nuclear atom is largely empty space), but it contains all the positive charge and at least 99.95% of the total mass of the atom.
Based on these results, Ernest Rutherford proposed a new model of the atom. He postulated that the positive charge in an atom is concentrated in a small region (in comparison to the rest of the atom) called a nucleus at the center of the atom with electrons existing in orbits around it. Furthermore, the nucleus is responsible for most of the mass of the atom.
The volume of an atom is about 15 orders of magnitude largerthan the volume of a nucleus. For uranium atom, the Van der Waals radius is about 186 pm = 1.86 ×10−10 m. The Van der Waals radius, rw, of an atom is the radius of an imaginary hard sphere representing the distance of closest approach for another atom. Assuming spherical shape, the uranium atom have volume of about 26.9 ×10−30 m3. But this “huge” space is occupied primarily by electrons, because the nucleus occupies only about 1721×10−45 m3 of space. These electrons together weigh only a fraction (let say 0.05%) of entire atom.
It may seem, that the space and in fact the matter is empty, but it is not. Due to the quantum nature of electrons, the electrons are not point particles, they are smeared out over the whole atom. The classical description cannot be used to describe things on the atomic scale. On the atomic scale, physicists have found that quantum mechanics describes things very well on that scale. Particle locations in quantum mechanics are not at an exact position, they are described by a probability density function. Therefore the space in an atom (between electrons and an atomic nucleus) is not empty, but it is filled by a probability density function of electrons (usually known as “electron cloud“).
Failure of Rutherford Model
It must be noted, the Rutherford model of the atom was not the first model, which proposed a nuclear structure. The idea of a nuclear structure was previously proposed in 1903 by a Japanese physicist Hantaro Nagaoka, who rejected Thomson’s model on the grounds that opposite charges are impenetrable.His model was known as the Saturnian model of the atom and according to this model the atom consists of a massive positive centre surrounded by a number of orbiting electrons, in the manner of Saturn and its rings.
Nagaoka’s planetary model had two predictions:
- a very massive atomic center (in analogy to a very massive planet)
- electrons revolving around the nucleus, bound by electrostatic forces
Both predictions were successfully confirmed by Ernest Rutherford in 1911, however, other details of the model was incorrect. Notwithstanding the Rutherford model of the atom was really very close to modern concept of the atom, it was based on classical physics. But neither classical physics nor the Rutherford model can explain the following problem. Why the negatively charged electrons are prevented from falling into the positively charged nucleus? Forces between static electrically charged particles are governed by the Coulomb’s law:
Rutherford suggested that perhaps the electrons revolve in orbits about the nucleus. In classical mechanics, a condition for the dynamic stability of such systems of rotating particles is that only forces of attraction act between its components.
Classical physics also states that any accelerating electric charge (either oscillating or revolving) emits electromagnetic radiation. As a result, an electron orbiting inside an atom should be continually losing energy and it should spiral into the nucleus within a fraction of a second. In fact, physicists calculated that the electron should lose all of its energy and spiral down into the proton in only about 0.000000000001 second, which means that every atoms should not exist longer than a mere 10-12 seconds.
The solution to the problem of the stability of the electrons in an atom was provided by young Danish physicist Niels Bohr working with Ernest Rutherford at the University of Manchester in 1913. His model adopted Planck’s quantum hypothesis and he proposed a model in which the electrons of an atom were assumed to orbit the nucleus but could only do so in a finite set of orbits. He postulated that an atom emits or absorbs energy only in discrete quanta corresponding to absorption or radiation of a photon.
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