Material Properties

Positron Interactions

The coulomb forces that constitute the major mechanism of energy loss for electrons are present for either positive or negative charge on the particle and constitute the major mechanism of energy loss also for positrons. Whatever the interaction involves a repulsive or attractive force between the incident particle and orbital electron (or atomic nucleus), the impulse and energy transfer for particles of equal mass are about the same. Therefore positrons interact similarly with matter when they are energetic. The track of positrons in material is similar to the track of electrons. Even their specific energy loss and range are about the same for equal initial energies.

At the end of their path, positrons differ significantly from electrons. When a positron (antimatter particle) comes to rest, it interacts with an electron (matter particle), resulting in the annihilation of the both particles and the complete conversion of their rest mass to pure energy (according to the E=mc² formula) in the form of two oppositely directed 0.511 MeV gamma rays (photons).

Positron Annihilation

Electron–positron annihilation occurs when a negatively charged electron and a positively charged positron collide.When a low-energy electron annihilates a low-energy positron (antiparticle of electron), they can only produce two or more photons (gamma rays). The production of only one photon is forbidden because of conservation of linear momentum and total energy. The production of another particle is also forbidden because of both particles (electron-positron) together do not carry enough mass-energy to produce heavier particles. When an electron and a positron collide, they annihilate resulting in the complete conversion of their rest mass to pure energy (according to the E=mc² formula) in the form of two oppositely directed 0.511 MeV gamma rays (photons).

e⁻ + e⁺ → γ + γ (2x 0.511 MeV)

This process must satisfy a number of conservation laws, including:

• Conservation of electric charge. The net charge before and after is zero.
• Conservation of linear momentum and total energy. T
• Conservation of angular momentum.

See also:

Cherenkov Radiation

See also:

Beta Particle

See also:

Positron Annihilation

Positron Annihilation

Electron–positron annihilation occurs when a negatively charged electron and a positively charged positron collide.When a low-energy electron annihilates a low-energy positron (antiparticle of electron), they can only produce two or more photons (gamma rays). The production of only one photon is forbidden because of conservation of linear momentum and total energy. The production of another particle is also forbidden because of both particles (electron-positron) together do not carry enough mass-energy to produce heavier particles. When an electron and a positron collide, they annihilate resulting in the complete conversion of their rest mass to pure energy (according to the E=mc² formula) in the form of two oppositely directed 0.511 MeV gamma rays (photons).

e⁻ + e⁺ → γ + γ (2x 0.511 MeV)

This process must satisfy a number of conservation laws, including:

• Conservation of electric charge. The net charge before and after is zero.
• Conservation of linear momentum and total energy. T
• Conservation of angular momentum.

See also:

Positron Interactions

See also:

Beta Particle

Before Albert Einstein, notably the German physicist Max Planck had prepared the way for the concept by explaining that objects that emit and absorb light do so only in amounts of energy that are quantized, that means every change of energy can occur only by certain particular discrete amounts and the object cannot change energy in any arbitrary way. The concept of modern photon came into general use after the physicist Arthur H. Compton demonstrated (1923) the corpuscular nature of X-rays. This was the validation that  Einstein’s hypothesis that light itself is quantized.

The term photon comes from Greek phōtos, “light” and a photon is usually denoted by the symbol γ (gamma). The photons are also symbolized by hν (in chemistry and optical engineering), where h is Planck’s constant and the Greek letter ν (nu) is the photon’s frequency. The radiation frequency is key parameter of all photons, because it determines the energy of a photon. Photons are categorized according to the energies from low-energy radio waves and infrared radiation, through visible light, to high-energy X-rays and gamma rays.

Photons are gauge bosons for electromagnetism, having no electric charge or rest mass and one unit of spin. Common to all photons is the speed of light, the universal constant of physics. In empty space, the photon moves at c (the speed of light – 299 792 458 metres per second).

Momentum of Photon

A photon, the quantum of electromagnetic radiation,  is an elementary particle, which is the force carrier of the electromagnetic force. The modern photon concept was developed (1905) by Albert Einstein to explain of the photoelectric effect, in which he proposed the existence of discrete energy packets during the transmission of light.

In 1916, Einstein extended his concept of light quanta (photons) by proposing that a quantum of light has linear momentum. Although a photon is massless, it has momentum, which is related to its energy E, frequency f, and wavelength by:

Thus, when a photon interacts with another object, energy and momentum are transferred, as if there were a collision between the photon and matter in the classical sense.

Momentum of a Photon – Compton Scattering

The Compton formula was published in 1923 in the Physical Review. Compton explained that the X-ray shift is caused by particle-like momentum of photons. Compton scattering formula is the mathematical relationship between the shift in wavelength and the scattering angle of the X-rays. In the case of Compton scattering the photon of frequency f collides with an electron at rest. Upon collision, the photon bounces off electron, giving up some of its initial energy (given by Planck’s formula E=hf), While the electron gains momentum (mass x velocity), the photon cannot lower its velocity. As a result of momentum conservation law, the photon must lower its momentum given by:

So the decrease in photon’s momentum must be translated into decrease in frequency (increase in wavelength Δλ = λ’ – λ). The shift of the wavelength increased with scattering angle according to the Compton formula:

where λ is the initial wavelength of photon λ’ is the wavelength after scattering, h is the Planck constant = 6.626 x 10^-34 J.s, m_e is the electron rest mass (0.511 MeV)c is the speed of light Θ is the scattering angle. The minimum change in wavelength (λ′ − λ) for the photon occurs when Θ = 0° (cos(Θ)=1) and is at least zero. The maximum change in wavelength (λ′ − λ) for the photon occurs when Θ = 180° (cos(Θ)=-1). In this case the photon transfers to the electron as much momentum as possible. The maximum change in wavelength can be derived from Compton formula:

The quantity h/m_ec is known as the Compton wavelength of the electron and is equal to 2.43×10⁻¹² m.

See also:

Beta Particle

See also:

Fundamental Particle

See also:

Gamma rays, also known as gamma radiation, refers to electromagnetic radiation (no rest mass, no charge) of a very high energies. Gamma rays are high-energy photons with very short wavelengths and thus very high frequency. Since the gamma rays are in substance only a very high-energy photons, they are very penetrating matter and are thus biologically hazardous. Gamma rays can travel thousands of feet in air and can easily pass through the human body.

Gamma rays are emitted by unstable nuclei in their transition from a high energy state to a lower state known as gamma decay. In most practical laboratory sources, the excited nuclear states are created in the decay of a parent radionuclide, therefore a gamma decay typically accompanies other forms of decay, such as alpha or beta decay.

Radiation and also gamma rays are all around us. In, around, and above the world we live in. It is a part of our natural world that has been here since the birth of our planet. Natural sources of gamma rays on Earth are inter alia gamma rays from naturally occurring radionuclides, particularly potassium-40.  Potasium-40 is a radioactive isotope of potassium which has a very long half-life of 1.251×10⁹ years (comparable to the age of Earth). This isotope can be found in soil, water also in meat and bananas. This is not the only example of natural source of gamma rays.

Discovery of Gamma Rays

Gamma rays were discovered shortly after discovery of X-rays. In 1896, French scientist Henri Becquerel discovered that uranium minerals could expose a photographic plate through another material. Becquerel presumed that uranium emitted some invisible light similar to X-rays, which were recently discovered by W.C.Roentgen. He called it “metallic phosphorescence”. In fact, Henri Becquerel had found gamma radiation being emitted by radioisotope ²²⁶Ra (radium), which is part of the Uranium series of uranium decay chain.
Gamma rays were first thought to be particles with mass, for example extremely energetic beta particles. This opinion failed, because this radiation cannot be deflected by a magnetic field, what indicated they had no charge. In 1914, gamma rays were observed to be reflected from crystal surfaces, proving they must be electromagnetic radiation, but with higher energy (higher frequency and shorter wavelengths).

Characteristics of Gamma Rays / Radiation

• Gamma rays are high-energy photons (about 10 000 times as much energy as the visible photons), the same photons as the photons forming the visible range of the electromagnetic spectrum – light.
• Photons (gamma rays and X-rays) can ionize atoms directly (despite they are electrically neutral) through the Photoelectric effect and the Compton effect, but secondary (indirect) ionization is much more significant.
• Gamma rays ionize matter primarily via indirect ionization.
• Although a large number of possible interactions are known, there are three key interaction mechanisms  with matter.
  • Photoelectric effect
  • Compton scattering
  • Pair production
• Gamma rays travel at the speed of light and they can travel thousands of meters in air before spending their energy.
• Since the gamma radiation is very penetrating matter, it must be shielded by very dense materials, such as lead or uranium.
• The distinction between X-rays and gamma rays is not so simple and has changed in recent decades.  According to the currently valid definition, X-rays are emitted by electrons outside the nucleus, while gamma rays are emitted by the nucleus.
• Gamma rays frequently accompany the emission of alpha and beta radiation.

Image: The relative importance of various processes of gamma radiation interactions with matter.

Photoelectric Effect

• The photoelectric effect dominates at low-energies of gamma rays.
• The photoelectric effect leads to the emission of photoelectrons from matter when light (photons) shines upon them.
• The maximum energy an electron can receive in any one interaction is hν.
• Electrons are only emitted by the photoelectric effect if photon reaches or exceeds a threshold energy.
• A free electron (e.g. from atomic cloud) cannot absorb entire energy of the incident photon. This is a result of the need to conserve both momentum and energy.
• The cross-section for the emission of n=1 (K-shell) photoelectrons is higher than that of n=2 (L-shell) photoelectrons. This is a result of the need to conserve momentum and energy.

Definition of Photoelectric effect

In the photoelectric effect, a photon undergoes an interaction with an electron which is bound in an atom. In this interaction the incident photon completely disappears and an energetic photoelectron is ejected by the atom from one of its bound shells. The kinetic energy of the ejected photoelectron (E_e) is equal to the incident photon energy (hν) minus the binding energy of the photoelectron in its original shell (E_b).

E_e=hν-E_b

Therefore photoelectrons are only emitted by the photoelectric effect if photon reaches or exceeds a threshold energy – the binding energy of the electron – the work function of the material. For gamma rays with energies of more than hundreds keV, the photoelectron carries off the majority of the incident photon energy – hν.

Following a photoelectric interaction, an ionized absorber atom is created with a vacancy in one of its bound shells. This vacancy is will be quickly filled by an electron from a shell with a lower binding energy (other shells) or through capture of a free electron from the material. The rearrangement of electrons from other shells creates another vacancy, which, in turn, is filled by an electron from an even lower binding energy shell. Therefore a cascade of more characteristic X-rays can be also generated. The probability of characteristic x-ray emission decreases as the atomic number of the absorber decreases. Sometimes , the emission of an Auger electron occurs.

Cross-Sections of Photoelectric Effect

At small values of gamma ray energy the photoelectric effect dominates. The mechanism is also enhaced for materials of high atomic number Z. It is not simple to derive analytic expression for the probability of photoelectric absorption of gamma ray per atom over all ranges of gamma ray energies. The probability of photoelectric absorption per unit mass is approximately proportional to:

τ_{(photoelectric)} = constant x Z^N/E^3.5

where Z is the atomic number, the exponent n varies between 4 and 5. E is the energy of the incident photon. The proportionality to higher powers of the atomic number Z is the main reason for using of high Z materials, such as lead or depleted uranium in gamma ray shields.

Although the probability of the photoelectric absorption of gamma photon decreases, in general, with increasing photon energy, there are sharp discontinuities in the cross-section curve. These are called “absoption edges” and they correspond to the binding energies of electrons from atom’s bound shells. For photons with the energy just above the edge, the photon energy is just sufficient to undergo the photoelectric interaction with electron from  bound shell, let say K-shell. The probability of such interaction is just above this edge much greater than that of photons of energy slightly below this edge. For gamma photons below this edge the interaction with electron from K-shell in energetically impossible and therefore the probability drops abruptly. These edges occur also at binding energies of electrons from other shells (L, M, N …..).

Compton Scattering

Key characteristics of Compton Scattering

• Compton scattering dominates at intermediate energies.
• It is the scattering of photons by atomic electrons  
• Photons undergo a wavelength shift called the Compton shift.
• The energy transferred to the recoil electron can vary from zero to a large fraction of the incident gamma ray energy

Definition of Compton Scattering

Compton scattering is the inelastic or nonclassical scattering of a photon (which may be an X-ray or gamma ray photon) by a charged particle, usually an electron. In Compton scattering, the incident gamma ray photon is deflected through an angle Θ with respect to its original direction. This deflection results in a decrease in energy (decrease in photon’s frequency) of the photon and is called the Compton effect. The photon transfers a portion of its energy to the recoil electron. The energy transferred to the recoil electron can vary from zero to a large fraction of the incident gamma ray energy, because all angles of scattering are possible. The Compton scattering was observed by A. H.Compton in 1923 at Washington University in St. Louis. Compton earned the Nobel Prize in Physics in 1927 for this new understanding about the particle-nature of photons.

Compton Scattering Formula

The Compton formula was published in 1923 in the Physical Review. Compton explained that the X-ray shift is caused by particle-like momentum of photons. Compton scattering formula is the mathematical relationship between the shift in wavelength and the scattering angle of the X-rays. In the case of Compton scattering the photon of frequency f collides with an electron at rest. Upon collision, the photon bounces off electron, giving up some of its initial energy (given by Planck’s formula E=hf), While the electron gains momentum (mass x velocity), the photon cannot lower its velocity. As a result of momentum conservetion law, the photon must lower its momentum given by:

So the decrease in photon’s momentum must be translated into decrease in frequency (increase in wavelength Δλ = λ’ – λ). The shift of the wavelength increased with scattering angle according to the Compton formula:

where

λ is the initial wavelength of photon

λ’ is the wavelength after scattering,

h is the Planck constant = 6.626 x 10^-34 J.s

m_e is the electron rest mass (0.511 MeV)

c is the speed of light

Θ is the scattering angle.

The minimum change in wavelength (λ′ − λ) for the photon occurs when Θ = 0° (cos(Θ)=1) and is at least zero. The maximum change in wavelength (λ′ − λ) for the photon occurs when Θ = 180° (cos(Θ)=-1). In this case the photon transfers to the electron as much momentum as possible.The maximum change in wavelength can be derived from Compton formula:

The quantity h/m_ec is known as the Compton wavelength of the electron and is equal to 2.43×10⁻¹² m.

Compton Scattering – Cross-Sections

The probability of Compton scattering per one interaction with an atom increases linearly with atomic number Z, because it depends on the number of electrons, which are available for scattering in the target atom. The angular distribution of photons scattered from a single free electron is described by the Klein-Nishina formula:

where ε = E₀/m_ec² and r₀ is the “classical radius of the electron” equal to about 2.8 x 10^-13 cm. The formula gives the probability of scattering a photon into the solid angle element dΩ = 2π sin Θ dΘ when the incident energy is E₀.

Compton Edge

In spectrophotometry, the Compton edge is a feature of the spectrograph that results from the Compton scattering in the scintillator or detector. This feature is due to photons that undergo Compton scattering with a scattering angle of 180° and then escape the detector. When a gamma ray scatters off the detector and escapes, only a fraction of its initial energy can be deposited in the sensitive layer of the detector. It depends on the scattering angle of the photon, how much energy will be deposited in the detector. This leads to a spectrum of energies. The Compton edge energy corresponds to full backscattered photon.

Inverse Compton Scattering

Inverse Compton scattering is the scattering of low energy photons to high energies by relativistic electrons. Relativistic electrons can boost energy of low energy photons by a potentially enormous amount (even gamma rays can be produced). This phenomenon is very important in astrophysics.

Positron-Electron Pair Production

In order for electron-positron pair production to occur, the electromagnetic energy of the photon must be above a threshold energy, which is equivalent to the rest mass of two electrons. The threshold energy (the total rest mass of produced particles) for electron-positron pair production is equal to 1.02MeV (2 x 0.511MeV) because the rest mass of a single electron is equivalent to 0.511MeV of energy.

If the original photon’s energy is greater than 1.02MeV, any energy above 1.02MeV is according to the conservation law split between the kinetic energy of motion of the two particles.

The presence of an electric field of a heavy atom such as lead or uranium is essential in order to satisfy conservation of momentum and energy. In order to satisfy both conservation of momentum and energy, the atomic nucleus must receive some momentum. Therefore a photon pair production in free space cannot occur.

Moreover, the positron is the anti-particle of the electron, so when a positron comes to rest, it interacts with another electron, resulting in the annihilation of the both particles and the complete conversion of their rest mass back to pure energy (according to the E=mc² formula) in the form of two oppositely directed 0.511 MeV gamma rays (photons). The pair production phenomenon is therefore connected with creation and destruction of matter in one reaction.

Positron-Electron Pair Production – Cross-Section

The probability of pair production, characterized by cross section, is a very complicated function based on quantum mechanics. In general the cross section increases approximately with the square of atomic number (σ_p ~ Z²) and increases with photon energy, but this dependence is much more complex.

Gamma Rays Attenuation

The total cross-section of interaction of a gamma rays with an atom is equal to the sum of all three mentioned partial cross-sections:

σ = σ_f + σ_C + σ_p 

• σ_f – Photoelectric effect

• σ_C – Compton scattering

• σ_p – Pair production

Depending on the gamma ray energy and the absorber material, one of the three partial cross-sections may become much larger than the other two. At small values of gamma ray energy the photoelectric effect dominates. Compton scattering dominates at intermediate energies. The compton scattering also increases with decreasing atomic number of matter, therefore the interval of domination is wider for light nuclei. Finally, electron-positron pair production dominates at high energies.

Based on the definition of interaction cross-section, the dependence of gamma rays intensity on thickness of absorber material can be derive. If monoenergetic gamma rays are collimated into a narrow beam and if the detector behind the material only detects the gamma rays that passed through that material without any kind of interaction with this material, then the dependence should be simple exponential attenuation of gamma rays. Each of these interactions removes the photon from the beam either by absorbtion or by scattering away from the detector direction. Therefore the interactions can be characterized by a fixed probability of occurance per unit path length in the absorber. The sum of these probabilities is called the linear attenuation coefficient:

μ = τ_{(photoelectric)} +  σ_(Compton) + κ_(pair)

Linear Attenuation Coefficient

The attenuation of gamma radiation can be then described by the following equation.

I=I₀.e^-μx

, where I is intensity after attenuation,  I_o is incident intensity,  μ is the linear attenuation coefficient (cm^-1), and physical thickness of absorber (cm).

The materials listed in the table beside are air, water and a different elements from carbon (Z=6) through to lead (Z=82) and their linear attenuation coefficients are given for three gamma ray energies. There are two main features of the linear attenuation coefficient:

• The linear attenuation coefficient increases as the atomic number of the absorber increases.
• The linear attenuation coefficient for all materials decreases with the energy of the gamma rays.

Half Value Layer

The half value layer expresses the thickness of absorbing material needed for reduction of the incident radiation intensity by a factor of two. There are two main features of the half value layer:

• The half value layer decreases as the atomic number of the absorber increases. For example 35 m of air is needed to reduce the intensity of a 100 keV gamma ray beam by a factor of two whereas just 0.12 mm of lead can do the same thing.
• The half value layer for all materials increases with the energy of the gamma rays. For example from 0.26 cm for iron at 100 keV to about 1.06 cm at 500 keV.

Mass Attenuation Coefficient

When characterizing an absorbing material, we can use sometimes the mass attenuation coefficient.  The mass attenuation coefficient is defined as the ratio of the linear attenuation coefficient and absorber density (μ/ρ). The attenuation of gamma radiation can be then described by the following equation:

I=I₀.e^-(μ/ρ).ρl

, where ρ is the material density, (μ/ρ) is the mass attenuation coefficient and ρ.l is the mass thickness. The measurement unit used for the mass attenuation coefficient cm²g^-1.

For intermediate energies the Compton scattering dominates and different absorbers have approximately equal mass attenuation coefficients. This is due to the fact that cross section of Compton scattering is proportional to the Z (atomic number) and therefore the coefficient is proportional to the material density ρ. At small values of gamma ray energy or at high values of gamma ray energy, where the coefficient is proportional to higher powers of the atomic number Z (for photoelectric effect σ_f ~ Z⁵; for pair production σ_p ~ Z²), the attenuation coefficient μ is not a constant.

Discovery of Gamma Rays

Gamma rays were discovered shortly after discovery of X-rays. In 1896, French scientist Henri Becquerel discovered that uranium minerals could expose a photographic plate through another material. Becquerel presumed that uranium emitted some invisible light similar to X-rays, which were recently discovered by W.C.Roentgen. He called it “metallic phosphorescence”. In fact, Henri Becquerel had found gamma radiation being emitted by radioisotope ²²⁶Ra (radium), which is part of the Uranium series of uranium decay chain.Gamma rays were first thought to be particles with mass, for example extremely energetic beta particles. This opinion failed, because this radiation cannot be deflected by a magnetic field, what indicated they had no charge. In 1914, gamma rays were observed to be reflected from crystal surfaces, proving they must be electromagnetic radiation, but with higher energy (higher frequency and shorter wavelengths).

See also:

Description of Gamma Rays

See also:

Gamma Ray

See also:

Characteristics of Gamma Rays

See above:See also:

Gamma Ray  

See also:

Discovery of Gamma Rays

Characteristics of Gamma Rays / Radiation

• Gamma rays are high-energy photons (about 10 000 times as much energy as the visible photons),
• The same photons as the photons forming the visible range of the electromagnetic spectrum – light.
• Photons (gamma rays and X-rays) can ionize atoms directly (despite they are electrically neutral) through the Photoelectric effect and the Compton effect, but secondary (indirect) ionization is much more significant.
• Gamma rays ionize matter primarily via indirect ionization.
• Although a large number of possible interactions are known, there are three key interaction mechanisms  with matter.
  • Photoelectric effect
  • Compton scattering
  • Pair production
• Gamma rays travel at the speed of light and they can travel thousands of meters in air before spending their energy.
• Since the gamma radiation is very penetrating matter, it must be shielded by very dense materials, such as lead or uranium.
• The distinction between X-rays and gamma rays is not so simple and has changed in recent decades.  According to the currently valid definition, X-rays are emitted by electrons outside the nucleus, while gamma rays are emitted by the nucleus.
• Gamma rays frequently accompany the emission of alpha and beta radiation.

See also:

Discovery of Gamma Rays

See also:

Gamma Ray

See also:

Photoelectric Effect

Description of Gamma Radiation

Gamma rays, also known as gamma radiation, refers to electromagnetic radiation (no rest mass, no charge) of a very high energies. Gamma rays are high-energy photons with very short wavelengths and thus very high frequency. Since the gamma rays are in substance only a very high-energy photons, they are very penetrating matter and are thus biologically hazardous. Gamma rays can travel thousands of feet in air and can easily pass through the human body.Gamma rays are emitted by unstable nuclei in their transition from a high energy state to a lower state known as gamma decay. In most practical laboratory sources, the excited nuclear states are created in the decay of a parent radionuclide, therefore a gamma decay typically accompanies other forms of decay, such as alpha or beta decay.Radiation and also gamma rays are all around us. In, around, and above the world we live in. It is a part of our natural world that has been here since the birth of our planet. Natural sources of gamma rays on Earth are inter alia gamma rays from naturally occurring radionuclides, particularly potassium-40.  Potassium-40 is a radioactive isotope of potassium which has a very long half-life of 1.251×10⁹ years (comparable to the age of Earth). This isotope can be found in soil, water also in meat and bananas. This is not the only example of natural source of gamma rays.

See also: Discovery of Gamma Rays

Characteristics of Gamma Rays / Radiation

Key features of gamma rays are summarized in following few points:

• Gamma rays are high-energy photons (about 10 000 times as much energy as the visible photons), the same photons as the photons forming the visible range of the electromagnetic spectrum – light.
• Photons (gamma rays and X-rays) can ionize atoms directly (despite they are electrically neutral) through the Photoelectric effect and the Compton effect, but secondary (indirect) ionization is much more significant.
• Gamma rays ionize matter primarily via indirect ionization.
• Although a large number of possible interactions are known, there are three key interaction mechanisms  with matter.
  • Photoelectric effect
  • Compton scattering
  • Pair production
• Gamma rays travel at the speed of light and they can travel thousands of meters in air before spending their energy.
• Since the gamma radiation is very penetrating matter, it must be shielded by very dense materials, such as lead or uranium.
• The distinction between X-rays and gamma rays is not so simple and has changed in recent decades.  According to the currently valid definition, X-rays are emitted by electrons outside the nucleus, while gamma rays are emitted by the nucleus.
• Gamma rays frequently accompany the emission of alpha and beta radiation.

Image: The relative importance of various processes of gamma radiation interactions with matter.

 

Photoelectric Effect

• The photoelectric effect dominates at low-energies of gamma rays.
• The photoelectric effect leads to the emission of photoelectrons from matter when light (photons) shines upon them.
• The maximum energy an electron can receive in any one interaction is hν.
• Electrons are only emitted by the photoelectric effect if photon reaches or exceeds a threshold energy.
• A free electron (e.g. from atomic cloud) cannot absorb entire energy of the incident photon. This is a result of the need to conserve both momentum and energy.
• The cross-section for the emission of n=1 (K-shell) photoelectrons is higher than that of n=2 (L-shell) photoelectrons. This is a result of the need to conserve momentum and energy.

See also: Albert Einstein and the Photoelectric Effect

Definition of Photoelectric effect

In the photoelectric effect, a photon undergoes an interaction with an electron which is bound in an atom. In this interaction the incident photon completely disappears and an energetic photoelectron is ejected by the atom from one of its bound shells. The kinetic energy of the ejected photoelectron (E_e) is equal to the incident photon energy (hν) minus the binding energy of the photoelectron in its original shell (E_b).

E_e=hν-E_b

Therefore photoelectrons are only emitted by the photoelectric effect if photon reaches or exceeds a threshold energy – the binding energy of the electron – the work function of the material. For gamma rays with energies of more than hundreds keV, the photoelectron carries off the majority of the incident photon energy – hν.

Following a photoelectric interaction, an ionized absorber atom is created with a vacancy in one of its bound shells. This vacancy is will be quickly filled by an electron from a shell with a lower binding energy (other shells) or through capture of a free electron from the material. The rearrangement of electrons from other shells creates another vacancy, which, in turn, is filled by an electron from an even lower binding energy shell. Therefore a cascade of more characteristic X-rays can be also generated. The probability of characteristic x-ray emission decreases as the atomic number of the absorber decreases. Sometimes , the emission of an Auger electron occurs.

 

Cross-Sections of Photoelectric Effect

At small values of gamma ray energy the photoelectric effect dominates. The mechanism is also enhaced for materials of high atomic number Z. It is not simple to derive analytic expression for the probability of photoelectric absorption of gamma ray per atom over all ranges of gamma ray energies. The probability of photoelectric absorption per unit mass is approximately proportional to:

τ_{(photoelectric)} = constant x Z^N/E^3.5

where Z is the atomic number, the exponent n varies between 4 and 5. E is the energy of the incident photon. The proportionality to higher powers of the atomic number Z is the main reason for using of high Z materials, such as lead or depleted uranium in gamma ray shields.

Although the probability of the photoelectric absorption of gamma photon decreases, in general, with increasing photon energy, there are sharp discontinuities in the cross-section curve. These are called “absoption edges” and they correspond to the binding energies of electrons from atom’s bound shells. For photons with the energy just above the edge, the photon energy is just sufficient to undergo the photoelectric interaction with electron from  bound shell, let say K-shell. The probability of such interaction is just above this edge much greater than that of photons of energy slightly below this edge. For gamma photons below this edge the interaction with electron from K-shell in energetically impossible and therefore the probability drops abruptly. These edges occur also at binding energies of electrons from other shells (L, M, N …..).

Compton Scattering

Key characteristics of Compton Scattering

• Compton scattering dominates at intermediate energies.
• It is the scattering of photons by atomic electrons  
• Photons undergo a wavelength shift called the Compton shift.
• The energy transferred to the recoil electron can vary from zero to a large fraction of the incident gamma ray energy

Definition of Compton Scattering

Compton scattering is the inelastic or nonclassical scattering of a photon (which may be an X-ray or gamma ray photon) by a charged particle, usually an electron. In Compton scattering, the incident gamma ray photon is deflected through an angle Θ with respect to its original direction. This deflection results in a decrease in energy (decrease in photon’s frequency) of the photon and is called the Compton effect. The photon transfers a portion of its energy to the recoil electron. The energy transferred to the recoil electron can vary from zero to a large fraction of the incident gamma ray energy, because all angles of scattering are possible. The Compton scattering was observed by A. H.Compton in 1923 at Washington University in St. Louis. Compton earned the Nobel Prize in Physics in 1927 for this new understanding about the particle-nature of photons.

Compton Scattering Formula

The Compton formula was published in 1923 in the Physical Review. Compton explained that the X-ray shift is caused by particle-like momentum of photons. Compton scattering formula is the mathematical relationship between the shift in wavelength and the scattering angle of the X-rays. In the case of Compton scattering the photon of frequency f collides with an electron at rest. Upon collision, the photon bounces off electron, giving up some of its initial energy (given by Planck’s formula E=hf), While the electron gains momentum (mass x velocity), the photon cannot lower its velocity. As a result of momentum conservetion law, the photon must lower its momentum given by:

So the decrease in photon’s momentum must be translated into decrease in frequency (increase in wavelength Δλ = λ’ – λ). The shift of the wavelength increased with scattering angle according to the Compton formula:

where

λ is the initial wavelength of photon

λ’ is the wavelength after scattering,

h is the Planck constant = 6.626 x 10^-34 J.s

m_e is the electron rest mass (0.511 MeV)

c is the speed of light

Θ is the scattering angle.

The minimum change in wavelength (λ′ − λ) for the photon occurs when Θ = 0° (cos(Θ)=1) and is at least zero. The maximum change in wavelength (λ′ − λ) for the photon occurs when Θ = 180° (cos(Θ)=-1). In this case the photon transfers to the electron as much momentum as possible.The maximum change in wavelength can be derived from Compton formula:

The quantity h/m_ec is known as the Compton wavelength of the electron and is equal to 2.43×10⁻¹² m.

Compton Scattering – Cross-Sections

The probability of Compton scattering per one interaction with an atom increases linearly with atomic number Z, because it depends on the number of electrons, which are available for scattering in the target atom. The angular distribution of photons scattered from a single free electron is described by the Klein-Nishina formula:

where ε = E₀/m_ec² and r₀ is the “classical radius of the electron” equal to about 2.8 x 10^-13 cm. The formula gives the probability of scattering a photon into the solid angle element dΩ = 2π sin Θ dΘ when the incident energy is E₀.

 

Compton Edge

In spectrophotometry, the Compton edge is a feature of the spectrograph that results from the Compton scattering in the scintillator or detector. This feature is due to photons that undergo Compton scattering with a scattering angle of 180° and then escape the detector. When a gamma ray scatters off the detector and escapes, only a fraction of its initial energy can be deposited in the sensitive layer of the detector. It depends on the scattering angle of the photon, how much energy will be deposited in the detector. This leads to a spectrum of energies. The Compton edge energy corresponds to full backscattered photon.

Inverse Compton Scattering

Inverse Compton scattering is the scattering of low energy photons to high energies by relativistic electrons. Relativistic electrons can boost energy of low energy photons by a potentially enormous amount (even gamma rays can be produced). This phenomenon is very important in astrophysics.

 

The atom consist of a small but massive nucleus surrounded by a cloud of rapidly moving electrons. The nucleus is composed of protons and neutrons. Total number of protons in the nucleus is called the atomic number of the atom and is given the symbol Z. The total electrical charge of the nucleus is therefore +Ze, where e (elementary charge) equals to 1,602 x 10^-19 coulombs. In a neutral atom there are as many electrons as protons moving about nucleus. It is the electrons that are responsible for the chemical bavavior of atoms, and which identify the various chemical elements.

Hydrogen (H), for example , consist of one electron and one proton. The number of neutrons in a nucleus is known as the neutron number and is given the symbol N. The total number of nucleons, that is, protons and neutrons in a nucleus, is equal to Z + N = A, where A is called the atomic mass number. The various species of atoms whose nuclei contain particular numbers of protons and neutrons are called nuclides. Each nuclide is denoted by chemical symbol of the element (this specifies Z) with tha atomic mass number as supescript.

Thus the symbol ¹H refers to the nuclide of hydrogen with a single proton as nucleus. ²H is the hydrogen nuclide with a neutron as well as a proton in the nucleus (2H is also called deuterium or heavy hydrogen). Atoms such as ¹H, ²H whose nuclei contain the same number of protons but different number of neutrons (different A) are known as isotopes. Uranium, for instance, has three isotopes occuring in nature – ²³⁸U, ²³⁵U and ²³⁴U. The stable isotopes (plus a few of the unstable isotopes) are the atoms that are found in the naturally occuring elements in nature. However, they are not found in equal amounts. Some isotopes of a given element are more abundant than others. For example 99,27% of naturally occuring uranium atoms are the isotope ²³⁸U, 0,72% are the isotope ²³⁵U and 0,0055% are the isotope ²³⁴U. Exact structure of atoms is described by Atomic Theory and Theory of Nuclear Structure.

Volume of an Atom and Nucleus

The atom consist of a small but massive nucleus surrounded by a cloud of rapidly moving electrons. The nucleus is composed of protons and neutrons. Typical nuclear radii are of the order 10⁻¹⁴ m. Assuming spherical shape, nuclear radii can be calculated according to following formula:

r = r₀ . A^1/3

where r₀ = 1.2 x 10^-15 m = 1.2 fm

If we use this approximation, we therefore expect the volume of the nucleus to be of the order of 4/3πr³ or 7,23 ×10⁻⁴⁵ m³ for hydrogen nuclei or 1721×10⁻⁴⁵ m³ for ²³⁸U nuclei. These are volumes of nuclei and atomic nuclei (protons and neutrons) contains of about 99.95% of mass of atom.

Is an atom an empty space?

The volume of an atom is about 15 orders of magnitude larger than the volume of a nucleus. For uranium atom, the Van der Waals radius is about 186 pm = 1.86 ×10⁻¹⁰ m. The Van der Waals radius, r_w, of an atom is the radius of an imaginary hard sphere representing the distance of closest approach for another atom.  Assuming spherical shape, the uranium atom have volume of about  26.9 ×10⁻³⁰ m³. But this “huge” space is occupied primarily by electrons, because the nucleus occupies only about 1721×10⁻⁴⁵ m³ of space. These electrons together weigh only a fraction (let say 0.05%) of entire atom.

It may seem, that the space and in fact the matter is empty, but it is not. Due to the quantum nature of electrons, the electrons are not point particles, they are smeared out over the whole atom. The classical description cannot be used to describe things on the atomic scale. On the atomic scale, physicists have found that quantum mechanics describes things very well on that scale. Particle locations in quantum mechanics are not at an exact position, they are described by a probability density function. Therefore the space in an atom (between electrons and an atomic nucleus) is not empty, but it is filled by a probability density function of electrons (usually known as  “electron cloud“).

• Atomic Theory. Atomic theory is a scientific theory of the nature of matter, which states that matter is composed of discrete units called atoms. The word atom comes from the Ancient Greek adjective atomos, meaning “uncuttable”. Today it is known that also atoms are divisible. Atomic Theory consist of many models and discoveries, which gradually formed this theory.
• Theory of Nuclear Structure. Understanding the structure of the atomic nucleus is one of the central challenges in modern nuclear physics.

See also:

Fundamental Particles

See also:

Atomic and Nuclear Physics

See also:

Mass and Energy

What is Radiation

Most general definition is that radiation is energy that comes from a source and travels through some material or through space. Light, heat and sound are types of radiation. This is very general definition, the kind of radiation discussed in this article is called ionizing radiation. Most people connect the term radiation only with ionizing radiation, but it is not correct. Radiation is all around us. In, around, and above the world we live in. It is a natural energy force that surrounds us. It is a part of our natural world that has been here since the birth of our planet. We should distinguish between:

• Non-ionizing radiation. The kinetic energy of particles (photons, electrons, etc.) of non-ionizing radiation is too small to produce charged ions when passing through matter. The particles (photons) have only sufficient energy to change the rotational, vibrational or electronic valence configurations of target molecules and atoms. Sunlight, radio waves, and cell phone signals are examples of non-ionizing (photon) radiation. However, it can still cause harm, like when you get a sunburn.

• Ionizing radiation. The kinetic energy of particles (photons, electrons, etc.) of ionizing radiation is sufficient and the particle can ionize (to form ion by losing electrons) target atoms to form ions. Simply ionizing radiation can knock electrons from an atom.

The boundary is not sharply defined, since different molecules and atoms ionize at different energies. This is typical for electromagnetic waves. Among electromagnetic waves belong, in order of increasing frequency (energy) and decreasing wavelength: radio waves, microwaves, infrared radiation, visible light, ultraviolet radiation, X-rays and gamma rays. Gamma rays, X-rays, and the higher ultraviolet part of the spectrum are ionizing, whereas the lower ultraviolet, visible light (including laser light), infrared, microwaves, and radio waves are considered non-ionizing radiation.

Forms of ionizing radiation

Ionizing radiation is categorized by the nature of the particles or electromagnetic waves that create the ionizing effect. These particles/waves have different ionization mechanisms, and may be grouped as:

• Directly ionizing. Charged particles (atomic nuclei, electrons, positrons, protons, muons, etc.) can ionize atoms directly by fundamental interaction through the Coulomb force if it carries sufficient kinetic energy. These particles must be moving at relativistic speeds to reach the required kinetic energy. Even photons (gamma rays and X-rays) can ionize atoms directly (despite they are electrically neutral) through the Photoelectric effect and the Compton effect, but secondary (indirect) ionization is much more significant.
  • Alpha radiation. Alpha radiation consist of alpha particles at high energy/speed. The production of alpha particles is termed alpha decay. Alpha particles consist of two protons and two neutrons bound together into a particle identical to a helium nucleus. Alpha particles are relatively large and carry a double positive charge. They are not very penetrating and a piece of paper can stop them. They travel only a few centimeters but deposit all their energies along their short paths.
  • Beta radiation. Beta radiation consist of free electrons or positrons at relativistic speeds. Beta particles (electrons) are much smaller than alpha particles. They carry a single negative charge. They are more penetrating than alpha particles, but thin aluminum metal can stop them. They can travel several meters but deposit less energy at any one point along their paths than alpha particles.
• Indirectly ionizing. Indirect ionizing radiation is electrically neutral particles and therefore does not interact strongly with matter. The bulk of the ionization effects are due to secondary ionizations.
  • Photon radiation (Gamma rays or X-rays). Photon radiation consist of high energy photons. These photons are particles/waves (Wave-Particle Duality) without rest mass or electrical charge. They can travel 10 meters or more in air. This is a long distance compared to alpha or beta particles. However, gamma rays deposit less energy along their paths. Lead, water, and concrete stop gamma radiation. Photons (gamma rays and X-rays) can ionize atoms directly through the Photoelectric effect and the Compton effect, where the relatively energetic electron is produced. The secondary electron will go on to produce multiple ionization events, therefore the secondary (indirect) ionization is much more significant.
  • Neutron radiation. Neutron radiation consist of free neutrons at any energies/speeds. Neutrons can be emitted by nuclear fission or by the decay of some radioactive atoms. Neutrons have zero electrical charge and cannot directly cause ionization. Neutrons ionize matter only indirectly. For example, when neutrons strike the hydrogen nuclei, proton radiation (fast protons) results. Neutrons can range from high speed, high energy particles to low speed, low energy particles (called thermal neutrons). Neutrons can travel hundreds of feet in air without any interaction.

Shielding of Ionizing Radiation

Radiation shielding simply means having some material between the source of radiation and you (or some device) that will absorb the radiation. The amount of shielding required, the type or material of shielding strongly depends on several factors. We are not talking about any optimisation.

In fact in some cases an inappropriate shielding may even worsen the radiation situation instead of protecting people from the ionizing radiation.  Basic factors, which have to be considered during proposal of radiation shielding, are:

• Type of the ionizing radiation to be shielded
• Energy spectrum of the ionizing radiation
• Length of exposure
• Distance from the source of the ionizing radiation
• Requirements on the attenuation of the ionizing radiation – ALARA or ALARP principles
• Design degree of freedom
• Other physical requirements (e.g. transparence in case of leaded glass screens)

See also: Shielding of Ionizing Radiation

• Shielding of Alpha Radiation
• Shielding of Beta Radiation
• Shielding of Positrons
• Shielding of Gamma Radiation
• Shielding of Neutrons

Shielding in Nuclear Power Plants

Generally in nuclear industry the radiation shielding has many purposes. In nuclear power plants the main purpose is to reduce the radiation exposure to persons and staff in the vicinity of radiation sources. In NPPs the main source of radiation is conclusively the nuclear reactor and its reactor core. Nuclear reactors are in generall powerful sources of entire spectrum of types of ionizing radiation. Shielding used for this purpose is called biological shielding.

But this is not the only purpose of radiation shielding. Shields are also used in some reactors to reduce the intensity of gamma rays or neutrons incident on the reactor vessel. This radiation shielding protects the reactor vessel and its internals (e.g. the core support barrel) from the excessive heating due to gamma ray absorption fast neutron moderation. Such shields are usually referred to as thermal shields.

See also: Neutron Reflector

A little strange radiation shielding is usually used to protect material of reactor pressure vessel (especially in PWR power plants). Structural materials of pressure vessel and reactor internals are damaged especially by fast neutrons. Fast neutrons create structural defects, which in result lead to embrittlement of material of pressure vessel. In order to minimize the neutron flux at the vessel wall, also core loading strategy can be modified. In “out-in” fuel loading strategy fresh fuel assemblies are placed at the periphery of the core.  This configuration causes high neutron fluence at the vessel wall. Therefore the “in-out” fuel loading strategy (with low leakage loading patterns – L3P) has been adopted at many nuclear power plants. In contrast to “out-in” strategy, low leakage cores have fresh fuel assemblies in the second row, not at the periphery of the core. The periphery contains fuel with higher fuel burnup and lower relative power and serves as the very sophisticated radiation shield.

In nuclear power plants the central problem is to shield against gamma rays and neutrons, because the ranges of charged particles (such as beta particles and alpha particles) in matter are very short. On the other hand we must deal with shielding of all types of radiation, because each nuclear reactor is a significant source of all types of ionizing radiation.

See also:

Mass and Energy

See also:

Atomic and Nuclear Physics

See also:

Nuclear Stability