What is Electrolytic-tough Pitch Copper – ETP – Characteristics and Uses – Definition

Electrolytic tough pitch copper, UNS C11000, is pure copper (with a maximum of 0.0355% of impurities) refined by electrolytic refining process and it is the most widely used grade of copper all over the world. ETP has a minimum conductivity rating of 100% IACS

High purity copper is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a reddish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement. High purity copper has the ultimate strength of approximately 210 MPa, and yield strength of 33 Mpa, which limits its usability in industrial applications. But similarly as for other alloys , copper may be strengthened. The main strengthening mechanism is alloying in Cu-based alloys.

Properties of Copper

Copper is a soft, tough, ductile and malleable material. These properties make copper extremely suitable for tube forming, wire drawing, spinning and deep drawing. The other key properties exhibited by copper and its alloys include:

  • Excellent thermal conductivity. Copper has a 60% higher thermal conductivity rating than aluminium, so it is better able to reduce thermal hot spots in electrical wiring systems. The electrical and thermal conductivities of metals originate from the fact that their outer electrons are delocalized.
  • Excellent electrical conductivity. The conductivity of copper is 97% that of silver. Due to its much lower cost and greater abundance, copper has traditionally been the standard material used for electricity transmission applications. However, aluminium is usually used in overhead high-voltage power lines because it has about half the weight and lower cost of a comparable resistance copper cable. At a given temperature, the thermal and electrical conductivities of metals are proportional, but raising the temperature increases the thermal conductivity while decreasing the electrical conductivity. This behavior is quantified in the Wiedemann–Franz law.
  • Good corrosion resistance. Copper does not react with water, but it does slowly react with atmospheric oxygen to form a layer of brown-black copper oxide which, unlike the rust that forms on iron in moist air, protects the underlying metal from further corrosion (passivation). Copper nickel alloys, aluminium brass, and aluminium demonstrate superior resistance to saltwater corrosion.
  • Good biofouling resistance
  • Good machinability. Machining of copper is possible, although alloys are preferred for good machinability in creating intricate parts.
  • Retention of mechanical and electrical properties at cryogenic temperatures
  • Diamagnetic

Electrolytic-tough pitch (ETP) copper

pure copperElectrolytic tough pitch copper, UNS C11000, is pure copper (with a maximum of 0.0355% of impurities) refined by electrolytic refining process and it is the most widely used grade of copper all over the world. ETP has a minimum conductivity rating of 100% IACS and is required to be 99.9% pure. It has 0.02% to 0.04% oxygen content (typical). Electrical wiring is the most important market for the copper industry. This includes structural power wiring, power distribution cable, appliance wire, communications cable, automotive wire and cable, and magnet wire. Roughly half of all copper mined is used for electrical wire and cable conductors. Pure copper has the best electrical and thermal conductivity of any commercial metal. The conductivity of copper is 97% that of silver. Due to its much lower cost and greater abundance, copper has traditionally been the standard material used for electricity transmission applications.

According to the Copper Development Association:

„The term ‘tough pitch’ originates from the time when molten copper, after refining, was cast into ingot moulds. During refining the copper was oxidised to remove impurities then reduced by hydrogen to give the correct oxygen level. To monitor this process, a small sample was taken and the solidification surface observed. If the surface sunk there was too much oxygen; if it was raised there was too much hydrogen. If it was level (correct pitch), the oxygen was correct, and the properties good; in other words ‘tough’, hence tough pitch.“

Source: https://copperalliance.org

 

Properties of Electrolytic-tough pitch (ETP) copper

Material properties are intensive properties, that means they are independent of the amount of mass and may vary from place to place within the system at any moment. The basis of materials science involves studying the structure of materials, and relating them to their properties (mechanical, electrical etc.). Once a materials scientist knows about this structure-property correlation, they can then go on to study the relative performance of a material in a given application. The major determinants of the structure of a material and thus of its properties are its constituent chemical elements and the way in which it has been processed into its final form.

Mechanical Properties of Electrolytic-tough pitch (ETP) copper

Materials are frequently chosen for various applications because they have desirable combinations of mechanical characteristics. For structural applications, material properties are crucial and engineers must take them into account.

Strength of Copper Alloys

In mechanics of materials, the strength of a material is its ability to withstand an applied load without failure or plastic deformation. Strength of materials basically considers the relationship between the external loads applied to a material and the resulting deformation or change in material dimensions. Strength of a material is its ability to withstand this applied load without failure or plastic deformation.

Ultimate Tensile Strength

Ultimate tensile strength of electrolytic-tough pitch (ETP) copper it is about 250 MPa.

Yield Strength - Ultimate Tensile Strength - Table of MaterialsThe ultimate tensile strength is the maximum on the engineering stress-strain curve. This corresponds to the maximum stress that can be sustained by a structure in tension. Ultimate tensile strength is often shortened to “tensile strength” or even to “the ultimate.”  If this stress is applied and maintained, fracture will result. Often, this value is significantly more than the yield stress (as much as 50 to 60 percent more than the yield for some types of metals). When a ductile material reaches its ultimate strength, it experiences necking where the cross-sectional area reduces locally. The stress-strain curve contains no higher stress than the ultimate strength. Even though deformations can continue to increase, the stress usually decreases after the ultimate strength has been achieved. It is an intensive property; therefore its value does not depend on the size of the test specimen. However, it is dependent on other factors, such as the preparation of the specimen, the presence or otherwise of surface defects, and the temperature of the test environment and material. Ultimate tensile strengths vary from 50 MPa for an aluminum to as high as 3000 MPa for very high-strength steels.

Yield Strength

Proof strength of electrolytic-tough pitch (ETP) copper is between 60-300 MPa.

The yield point is the point on a stress-strain curve that indicates the limit of elastic behavior and the beginning plastic behavior. Yield strength or yield stress is the material property defined as the stress at which a material begins to deform plastically whereas yield point is the point where nonlinear (elastic + plastic) deformation begins. Prior to the yield point, the material will deform elastically and will return to its original shape when the applied stress is removed. Once the yield point is passed, some fraction of the deformation will be permanent and non-reversible. Some steels and other materials exhibit a behaviour termed a yield point phenomenon. Yield strengths vary from 35 MPa for a low-strength aluminum to greater than 1400 MPa for very high-strength steels.

Young’s Modulus of Elasticity

Young’s modulus of elasticity of electrolytic-tough pitch (ETP) copper is about 120 GPa.

The Young’s modulus of elasticity is the elastic modulus for tensile and compressive stress in the linear elasticity regime of a uniaxial deformation and is usually assessed by tensile tests. Up to a limiting stress, a body will be able to recover its dimensions on removal of the load. The applied stresses cause the atoms in a crystal to move from their equilibrium position. All the atoms are displaced the same amount and still maintain their relative geometry. When the stresses are removed, all the atoms return to their original positions and no permanent deformation occurs. According to the Hooke’s law, the stress is proportional to the strain (in the elastic region), and the slope is Young’s modulus. Young’s modulus is equal to the longitudinal stress divided by the strain.

Hardness of Electrolytic-tough pitch (ETP) copper

Vickers hardness of electrolytic-tough pitch (ETP) copper depends greatly on the temper of the material, but it is between 50 – 150 HV.

Brinell hardness number

Rockwell hardness test is one of the most common indentation hardness tests, that has been developed for hardness testing. In contrast to Brinell test, the Rockwell tester measures the depth of penetration of an indenter under a large load (major load) compared to the penetration made by a preload (minor load). The minor load establishes the zero position. The major load is applied, then removed while still maintaining the minor load. The difference between depth of penetration before and after application of the major load is used to calculate the Rockwell hardness number. That is, the penetration depth and hardness are inversely proportional. The chief advantage of Rockwell hardness is its ability to display hardness values directly. The result is a dimensionless number noted as HRA, HRB, HRC, etc., where the last letter is the respective Rockwell scale.

The Rockwell C test is performed with a Brale penetrator (120°diamond cone) and a major load of 150kg.

Thermal Properties of Electrolytic-tough pitch (ETP) copper

Thermal properties of materials refer to the response of materials to changes in their temperature and to the application of heat. As a solid absorbs energy in the form of heat, its temperature rises and its dimensions increase. But different materials react to the application of heat differently.

Heat capacity, thermal expansion, and thermal conductivity are properties that are often critical in the practical use of solids.

Melting Point of Electrolytic-tough pitch (ETP) copper

Melting point of electrolytic-tough pitch (ETP) copper is around 1085°C.

In general, melting is a phase change of a substance from the solid to the liquid phase. The melting point of a substance is the temperature at which this phase change occurs. The melting point also defines a condition in which the solid and liquid can exist in equilibrium.

Thermal Conductivity of Electrolytic-tough pitch (ETP) copper

The thermal conductivity of electrolytic-tough pitch (ETP) copper is 394 W/(m.K).

The heat transfer characteristics of a solid material are measured by a property called the thermal conductivity, k (or λ), measured in W/m.K. It is a measure of a substance’s ability to transfer heat through a material by conduction. Note that Fourier’s law applies for all matter, regardless of its state (solid, liquid, or gas), therefore, it is also defined for liquids and gases.

The thermal conductivity of most liquids and solids varies with temperature. For vapors, it also depends upon pressure. In general:

thermal conductivity - definition

Most materials are very nearly homogeneous, therefore we can usually write k = k (T). Similar definitions are associated with thermal conductivities in the y- and z-directions (ky, kz), but for an isotropic material the thermal conductivity is independent of the direction of transfer, kx = ky = kz = k.

Electrical Conductivity of Electrolytic-tough pitch (ETP) copper

The electrical conductivity of electrolytic-tough pitch (ETP) copper is 101% IACS (around 58.6 MS/m).

Electrical resistivity and its converse, electrical conductivity, is a fundamental property of a material that quantifies how strongly it resists or conducts the flow of electric current. A low resistivity indicates a material that readily allows the flow of electric current. The symbol of resistivity is usually the Greek letter ρ (rho). The SI unit of electrical resistivity is the ohm-metre (Ω⋅m). Note that, electrical resistivity is not the same as electrical resistance. Electrical resistance is expressed in Ohms. While resistivity is a material property, resistance is the property of an object.

References:
Materials Science:

U.S. Department of Energy, Material Science. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.
U.S. Department of Energy, Material Science. DOE Fundamentals Handbook, Volume 2 and 2. January 1993.
William D. Callister, David G. Rethwisch. Materials Science and Engineering: An Introduction 9th Edition, Wiley; 9 edition (December 4, 2013), ISBN-13: 978-1118324578.
Eberhart, Mark (2003). Why Things Break: Understanding the World by the Way It Comes Apart. Harmony. ISBN 978-1-4000-4760-4.
Gaskell, David R. (1995). Introduction to the Thermodynamics of Materials (4th ed.). Taylor and Francis Publishing. ISBN 978-1-56032-992-3.
González-Viñas, W. & Mancini, H.L. (2004). An Introduction to Materials Science. Princeton University Press. ISBN 978-0-691-07097-1.
Ashby, Michael; Hugh Shercliff; David Cebon (2007). Materials: engineering, science, processing and design (1st ed.). Butterworth-Heinemann. ISBN 978-0-7506-8391-3.
J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.

See above:
Copper Alloys

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