Nick Connor

Exothermic vs. Endothermic Reactions

For reactions in which there is an increase in the kinetic energy of the products Q is positive. The positive Q reactions are said to be exothermic (or exergic). There is a net release of energy, since the kinetic energy of the final state is greater than the kinetic energy of the initial state.

For reactions in which there is a decrease in the kinetic energy of the products Q is negative. The negative Q reactions are said to be endothermic (or endoergic) and they require a net energy input.

The Q-value of this reaction is given by:

Q = [m_a + m_A – (m_b + m_B)]c²

which is the same as the excess kinetic energy of the final products:

Q = T_final – T_initial

   = T_b + T_B – (T_a + T_A)

See also: Q-value Calculator

See also: E=mc²

Exothermic Reactions

Exothermic Reaction - DT fusion

The DT fusion reaction of deuterium and tritium is particularly interesting because of its potential of providing energy for the future. Calculate the reaction Q-value.

3T (d, n) 4He

The atom masses of the reactants and products are:

m(³T) = 3.0160 amu

m(²D) = 2.0141 amu

m(¹n) = 1.0087 amu

m(⁴He) = 4.0026 amu

Using the mass-energy equivalence, we get the Q-value of this reaction as:

Q = {(3.0160+2.0141) [amu] – (1.0087+4.0026) [amu]} x 931.481 [MeV/amu]

= 0.0188 x 931.481 = 17.5 MeV

Exothermic Reaction - Tritium

Tritium is a byproduct in nuclear reactors. Most of the tritium produced in nuclear power plants stems from the boric acid, which is commonly used as a chemical shim to compensate an excess of initial reactivity. Main reaction, in which the tritium is generated from boron is below:

10B(n,2*alpha)T

This reaction of a neutron with an isotope ¹⁰B is the main way, how radioactive tritium in primary circuit of all PWRs is generated. Note that, this reaction is a threshold reaction due to its cross-section.

Calculate the reaction Q-value.

The atom masses of the reactants and products are:

m(¹⁰B) = 10.01294 amu

m(¹n) = 1.00866 amu

m(³T) = 3.01604 amu

m(⁴He) = 4.0026 amu

Using the mass-energy equivalence, we get the Q-value of this reaction as:

Q = {(10.0129+1.00866) [amu] – (3.01604+2 x 4.0026) [amu]} x 931.481 [MeV/amu]

= 0.00036 x 931.481 = 0.335 MeV

Endothermic Reactions

Endothermic Reaction - Photoneutrons

In nuclear reactors the gamma radiation plays a significant role also in reactor kinetics and in a subcriticality control. Especially in nuclear reactors with D₂O moderator (CANDU reactors) or with Be reflectors (some experimental reactors). Neutrons can be produced also in (γ, n) reactions and therefore they are usually referred to as photoneutrons.

A high energy photon (gamma ray) can under certain conditions eject a neutron from a nucleus. It occurs when its energy exceeds the binding energy of the neutron in the nucleus. Most nuclei have binding energies in excess of 6 MeV, which is above the energy of most gamma rays from fission. On the other hand there are few nuclei with sufficiently low binding energy to be of practical interest. These are: ²D, ⁹Be, ⁶Li, ⁷Li and ¹³C. As can be seen from the table the lowest threshold have ⁹Be with 1.666 MeV and ²D with 2.226 MeV.

In case of deuterium, neutrons can be produced by the interaction of gamma rays (with a minimum energy of 2.22 MeV) with deuterium:

The reaction Q-value is calculated below:

The atom masses of the reactant and products are:

m(²D) = 2.01363 amu

m(¹n) = 1.00866 amu

m(¹H) = 1.00728 amu

Using the mass-energy equivalence, we get the Q-value of this reaction as:

Q = {2.01363 [amu] – (1.00866+1.00728) [amu]} x 931.481 [MeV/amu]

= -0.00231 x 931.481 = -2.15 MeV

See also:

Nuclear Reactions

Endothermic Reactions

In nuclear and particle physics the energetics of nuclear reactions is determined by the Q-value of that reaction. The Q-value of the reaction is defined as the difference between the sum of the masses of the initial reactants and the sum of the masses of the final products, in energy units (usually in MeV).

Consider a typical reaction, in which the projectile a and the target A gives place to two products, B and b. This can also be expressed in the notation that we used so far, a + A → B + b, or even in a more compact notation, A(a,b)B.

See also: E=mc²

The Q-value of this reaction is given by:

Q = [m_a + m_A – (m_b + m_B)]c²

which is the same as the excess kinetic energy of the final products:

Q = T_final – T_initial

   = T_b + T_B – (T_a + T_A)

For reactions in which there is a decrease in the kinetic energy of the products Q is negative. The negative Q reactions are said to be endothermic (or endoergic) and they require a net energy input.

See also: Q-value Calculator

Example of Endothermic Reaction – Photoneutrons

In nuclear reactors the gamma radiation plays a significant role also in reactor kinetics and in a subcriticality control. Especially in nuclear reactors with D₂O moderator (CANDU reactors) or with Be reflectors (some experimental reactors). Neutrons can be produced also in (γ, n) reactions and therefore they are usually referred to as photoneutrons.

A high energy photon (gamma ray) can under certain conditions eject a neutron from a nucleus. It occurs when its energy exceeds the binding energy of the neutron in the nucleus. Most nuclei have binding energies in excess of 6 MeV, which is above the energy of most gamma rays from fission. On the other hand there are few nuclei with sufficiently low binding energy to be of practical interest. These are: ²D, ⁹Be, ⁶Li, ⁷Li and ¹³C. As can be seen from the table the lowest threshold have ⁹Be with 1.666 MeV and ²D with 2.226 MeV.

In case of deuterium, neutrons can be produced by the interaction of gamma rays (with a minimum energy of 2.22 MeV) with deuterium:

The reaction Q-value is calculated below:

The atom masses of the reactant and products are:

m(²D) = 2.01363 amu

m(¹n) = 1.00866 amu

m(¹H) = 1.00728 amu

Using the mass-energy equivalence, we get the Q-value of this reaction as:

Q = {2.01363 [amu] – (1.00866+1.00728) [amu]} x 931.481 [MeV/amu]

= -0.00231 x 931.481 = -2.15 MeV

Example: Endothermic Reaction – (α,n) reaction

Calculate the reaction Q-value of the following reaction:

7Li (α, n) 10B

The atom masses of the reactants and products are:

m(⁴He) = 4.0026 amu

m(⁷Li) = 7.0160 amu

m(¹n) = 1.0087 amu

m(¹⁰B) = 10.01294 amu

Using the mass-energy equivalence, we get the Q-value of this reaction as:

Q = {(7.0160+4.0026) [amu] – (1.0087+10.01294) [amu]} x 931.481 [MeV/amu]

= 0.00304 x 931.481 = -2.83 MeV

See also:

Nuclear Reactions

Exothermic Reactions

In nuclear and particle physics the energetics of nuclear reactions is determined by the Q-value of that reaction. The Q-value of the reaction is defined as the difference between the sum of the masses of the initial reactants and the sum of the masses of the final products, in energy units (usually in MeV).

Consider a typical reaction, in which the projectile a and the target A gives place to two products, B and b. This can also be expressed in the notation that we used so far, a + A → B + b, or even in a more compact notation, A(a,b)B.

See also: E=mc²

The Q-value of this reaction is given by:

Q = [m_a + m_A – (m_b + m_B)]c²

which is the same as the excess kinetic energy of the final products:

Q = T_final – T_initial

   = T_b + T_B – (T_a + T_A)

For reactions in which there is an increase in the kinetic energy of the products Q is positive. The positive Q reactions are said to be exothermic (or exergic). There is a net release of energy, since the kinetic energy of the final state is greater than the kinetic energy of the initial state.

See also: Q-value Calculator

Example of Exothermic Reaction – Nuclear Fission

Nuclear fission is a nuclear reaction in which the nucleus of an atom splits into smaller parts (lighter nuclei). The fission process often produces free neutrons and photons (in the form of gamma rays), and releases a large amount of energy.

From the nuclear binding energy curve and from the table it can be seen that, in the case of splitting a ²³⁵U nucleus into two parts, the binding energy of the fragments (A ≈ 120) together is larger than that of the original ²³⁵U nucleus. According to the Weizsaecker formula, the total energy released for such reaction will be approximately 235 x (8.5 – 7.6) ≈ 200 MeV (it can also be derived from nuclear binding curve).

The total energy released in a reactor per ²³⁵U fission is distributed as shown in the table.

Example of Exothermic Reaction – DT fusion

The DT fusion reaction of deuterium and tritium is particularly interesting because of its potential of providing energy for the future. Calculate the reaction Q-value.

3T (d, n) 4He

The atom masses of the reactants and products are:

m(³T) = 3.0160 amu

m(²D) = 2.0141 amu

m(¹n) = 1.0087 amu

m(⁴He) = 4.0026 amu

Using the mass-energy equivalence, we get the Q-value of this reaction as:

Q = {(3.0160+2.0141) [amu] – (1.0087+4.0026) [amu]} x 931.481 [MeV/amu]

= 0.0188 x 931.481 = 17.5 MeV

Example of Exothermic Reaction – Tritium in Reactors

Tritium is a byproduct in nuclear reactors. Most of the tritium produced in nuclear power plants stems from the boric acid, which is commonly used as a chemical shim to compensate an excess of initial reactivity. Main reaction, in which the tritium is generated from boron is below:

10B(n,2*alpha)T

This reaction of a neutron with an isotope ¹⁰B is the main way, how radioactive tritium in primary circuit of all PWRs is generated. Note that, this reaction is a threshold reaction due to its cross-section.

Calculate the reaction Q-value.

The atom masses of the reactants and products are:

m(¹⁰B) = 10.01294 amu

m(¹n) = 1.00866 amu

m(³T) = 3.01604 amu

m(⁴He) = 4.0026 amu

Using the mass-energy equivalence, we get the Q-value of this reaction as:

Q = {(10.0129+1.00866) [amu] – (3.01604+2 x 4.0026) [amu]} x 931.481 [MeV/amu]

= 0.00036 x 931.481 = 0.335 MeV

See also:

Nuclear Reactions

Q-value – Energetics of Nuclear Reactions

In nuclear and particle physics the energetics of nuclear reactions is determined by the Q-value of that reaction. The Q-value of the reaction is defined as the difference between the sum of the masses of the initial reactants and the sum of the masses of the final products, in energy units (usually in MeV).

Consider a typical reaction, in which the projectile a and the target A gives place to two products, B and b. This can also be expressed in the notation that we used so far, a + A → B + b, or even in a more compact notation, A(a,b)B.

See also: E=mc²

The Q-value of this reaction is given by:

Q = [m_a + m_A – (m_b + m_B)]c²

which is the same as the excess kinetic energy of the final products:

Q = T_final – T_initial

   = T_b + T_B – (T_a + T_A)

For reactions in which there is an increase in the kinetic energy of the products Q is positive. The positive Q reactions are said to be exothermic (or exergic). There is a net release of energy, since the kinetic energy of the final state is greater than the kinetic energy of the initial state.

For reactions in which there is a decrease in the kinetic energy of the products Q is negative. The negative Q reactions are said to be endothermic (or endoergic) and they require a net energy input.

See also: Q-value Calculator

Q-value of Exothermic Reactions

Q-value of Endothermic Reactions

See also:

Nuclear Reactions

Mass Defect

In special theory of relativity certain types of matter may be created or destroyed, but in all of these processes, the mass and energy associated with such matter remains unchanged in quantity. It was found the rest mass of an atomic nucleus is measurably smaller than the sum of the rest masses of its constituent protons, neutrons and electrons. Mass was no longer considered unchangeable in the closed system. The difference is a measure of the nuclear binding energy which holds the nucleus together. According to the Einstein relationship (E=mc²), this binding energy is proportional to this mass difference and it is known as the mass defect.

During the nuclear splitting or nuclear fusion, some of the mass of the nucleus gets converted into huge amounts of energy and thus this mass is removed from the total mass of the original particles, and the mass is missing in the resulting nucleus. The nuclear binding energies are enormous, they are on the order of a million times greater than the electron binding energies of atoms.

Examples of mass defect calculation

See also:

Laws of Conservation

Laws of Conservation

In physics, a conservation law states that a particular measurable property of an isolated physical system does not change as the system evolves over time. These properties are sometimes called “constants of the motion“. These quantities are said to be “conserved” and the conservation laws which result can be considered to be the most fundamental principles of mechanics. In mechanics, examples of conserved quantities are energy, momentum, and angular momentum. The laws of conservation are exact for an isolated system.

The Law of Conservation of Matter

The law of conservation of matter or principle of matter conservation states that the mass of an object or collection of objects never changes over time, no matter how the constituent parts rearrange themselves.

The mass can neither be created nor destroyed.

The law requires that during any nuclear reaction, radioactive decay or chemical reaction in an isolated system, the total mass of the reactants or starting materials must be equal to the mass of the products.

• Why a piece of wood weighs less after burning?
• Can a matter or some of its part disappear?

In the case of burned wood the problem was the measurement of the weight of released gases. Measurements of the weight of released gases was complicated, because of the buoyancy effect of the Earth’s atmosphere on the weight of gases. Once understood, the conservation of matter was of crucial importance in the progress from alchemy to the modern natural science of chemistry.

Law of Conservation of Energy

The law of conservation of energy is one of the basic laws of physics along with the conservation of mass and the conservation of momentum. The law of conservation of energy states that energy can change from one form into another, but it cannot be created or destroyed. Or the general definition is:

The total energy of an isolated system remains constant over time.

Energy can be defined as the capacity for doing work. It may exist in a variety of forms and may be transformed from one type of energy to another in hundreds of ways.

For example, burning gasoline to power cars is an energy conversion process we rely on. The chemical energy in gasoline is converted to thermal energy, which is then converted to mechanical energy that makes the car move. The mechanical energy has been converted to kinetic energy. When we use the brakes to stop a car, that kinetic energy is converted by friction back to heat, or thermal energy.

A consequence of the law of conservation of energy is that a perpetual motion machine of the first kind, which produces work without the input of energy, cannot exist.

The concept of energy conservation is widely used in many fields. In this article the following fields are discussed:

• Conservation of Mechanical Energy
• Conservation of Energy in Fluid Mechanics
• thermodynamics – The First Law of thermodynamics” href=”https://www.nuclear-power.com/laws-of-conservation/law-of-conservation-of-energy/first-law-thermodynamics/”>Conservation of Energy in thermodynamics
• Conservation of Energy in Electrical Circuits
• Conservation of Energy in Chemical Reactions
• Conservation of Energy in Special Relativity Theory
• Conservation of Energy in Nuclear Reactions

Law of Conservation of Mass-Energy – Mass-Energy Equivalence

At the beginning of the 20th century, the notion of mass underwent a radical revision. Mass lost its absoluteness. One of the striking results of Einstein’s theory of relativity is that mass and energy are equivalent and convertible one into the other. Equivalence of the mass and energy is described by Einstein’s famous formula E = mc². In words, energy equals mass multiplied by the speed of light squared. Because the speed of light is a very large number, the formula implies that any small amount of matter contains a very large amount of energy. The mass of an object was seen to be equivalent to energy, to be interconvertible with energy, and to increase significantly at exceedingly high speeds near that of light. The total energy of an object was understood to comprise its rest mass as well as its increase of mass caused by increase in kinetic energy.

In special theory of relativity certain types of matter may be created or destroyed, but in all of these processes, the mass and energy associated with such matter remains unchanged in quantity. It was found the rest mass an atomic nucleus is measurably smaller than the sum of the rest masses of its constituent protons, neutrons and electrons. Mass was no longer considered unchangeable in the closed system. The difference is a measure of the nuclear binding energy which holds the nucleus together. According to the Einstein relationship (E = mc²) this binding energy is proportional to this mass difference and it is known as the mass defect.

During the nuclear splitting or nuclear fusion, some of the mass of the nucleus gets converted into huge amounts of energy and thus this mass is removed from the total mass of the original particles, and the mass is missing in the resulting nucleus. The nuclear binding energies are enormous, they are of the order of a million times greater than the electron binding energies of atoms.

Generally, in both chemical and nuclear reactions, some conversion between rest mass and energy occurs, so that the products generally have smaller or greater mass than the reactants. Therefore the new conservation principle is the conservation of mass-energy.

See also: Energy Release from Fission

The Law of Conservation of Matter – Conservation of Mass

The law of conservation of matter or principle of matter conservation states that the mass of an object or collection of objects never changes over time, no matter how the constituent parts rearrange themselves.

The mass can neither be created nor destroyed.

The law requires that during any nuclear reaction, radioactive decay or chemical reaction in an isolated system, the total mass of the reactants or starting materials must be equal to the mass of the products.

Historically, already the ancient Greeks proposed the idea that the total amount of matter in the universe is constant. The principle of conservation of mass was first outlined by Mikhail Lomonosov in 1748. However, the law of conservation of matter (or the principle of mass/matter conservation) as a fundamental principle of physics was discovered in by Antoine Lavoisier in the late 18th century. It was of great importance in progressing from alchemy to modern chemistry. Before this discovery, there were questions like:

• Why a piece of wood weighs less after burning?
• Can a matter or some of its part disappear?

In the case of burned wood the problem was the measurement of the weight of released gases. Measurements of the weight of released gases was complicated, because of the buoyancy effect of the Earth’s atmosphere on the weight of gases. Once understood, the conservation of matter was of crucial importance in the progress from alchemy to the modern natural science of chemistry.

The Law of Conservation of Matter in Special Relativity Theory

At the beginning of the 20th century, the notion of mass underwent a radical revision. Mass lost its absoluteness. One of the striking results of Einstein’s theory of relativity is that mass and energy are equivalent and convertible one into the other. Equivalence of the mass and energy is described by Einstein’s famous formula E = mc². In words, energy equals mass multiplied by the speed of light squared. Because the speed of light is a very large number, the formula implies that any small amount of matter contains a very large amount of energy. The mass of an object was seen to be equivalent to energy, to be interconvertible with energy, and to increase significantly at exceedingly high speeds near that of light. The total energy of an object was understood to comprise its rest mass as well as its increase of mass caused by increase in kinetic energy.

In special theory of relativity certain types of matter may be created or destroyed, but in all of these processes, the mass and energy associated with such matter remains unchanged in quantity. It was found the rest mass an atomic nucleus is measurably smaller than the sum of the rest masses of its constituent protons, neutrons and electrons. Mass was no longer considered unchangeable in the closed system. The difference is a measure of the nuclear binding energy which holds the nucleus together. According to the Einstein relationship (E = mc²) this binding energy is proportional to this mass difference and it is known as the mass defect.

During the nuclear splitting or nuclear fusion, some of the mass of the nucleus gets converted into huge amounts of energy and thus this mass is removed from the total mass of the original particles, and the mass is missing in the resulting nucleus. The nuclear binding energies are enormous, they are of the order of a million times greater than the electron binding energies of atoms.

Generally, in both chemical and nuclear reactions, some conversion between rest mass and energy occurs, so that the products generally have smaller or greater mass than the reactants. Therefore the new conservation principle is the conservation of mass-energy.

See also: Energy Release from Fission

The Law of Conservation of Matter in Fluid Dynamics

This principle is generally known as the conservation of matter principle and states that the mass of an object or collection of objects never changes over time, no matter how the constituent parts rearrange themselves. This principle can be use in the analysis of flowing fluids. Conservation of mass in fluid dynamics states that all mass flow rates into a control volume are equal to all mass flow rates out of the control volume plus the rate of change of mass within the control volume. This principle is expressed mathematically by following equation:

ṁ_in = ṁ_out +^∆m⁄_∆t

Mass entering per unit time = Mass leaving per unit time + Increase of mass in the control volume per unit time

This equation describes nonsteady-state flow. Nonsteady-state flow refers to the condition where the fluid properties at any single point in the system may change over time. Steady-state flow refers to the condition where the fluid properties (temperature, pressure, and velocity) at any single point in the system do not change over time. But one of the most significant properties that is constant in a steady-state flow system is the system mass flow rate. This means that there is no accumulation of mass within any component in the system.

See also: Continuity Equation

Continuity Equation

The continuity equation is simply a mathematical expression of the principle of conservation of mass. For a control volume that has a single inlet and a single outlet, the principle of conservation of mass states that, for steady-state flow, the mass flow rate into the volume must equal the mass flow rate out.

ṁ_in = ṁ_out 

Mass entering per unit time = Mass leaving per unit time

This equation is called the continuity equation for steady one-dimensional flow. For a steady flow through a control volume with many inlets and outlets, the net mass flow must be zero, where inflows are negative and outflows are positive.

This principle can be applied to a streamtube such as that shown above. No fluid flows across the boundary made by the streamlines so mass only enters and leaves through the two ends of this streamtube section.

When a fluid is in motion, it must move in such a way that mass is conserved. To see how mass conservation places restrictions on the velocity field, consider the steady flow of fluid through a duct (that is, the inlet and outlet flows do not vary with time).

Differential Form of Continuity Equation

A general continuity equation can also be written in a differential form:

^∂⍴⁄_∂t + ∇ . (⍴ ͞v) = σ

where

• ∇ . is divergence,
• ρ is the density of quantity q,
• ⍴ ͞v is the flux of quantity q,
• σ is the generation of q per unit volume per unit time. Terms that generate (σ > 0) or remove (σ < 0) q are referred to as a “sources” and “sinks” respectively. If q is a conserved quantity (such as energy), σ is equal to 0.

See also:

Laws of Conservation

Forms of Ionizing Radiation

Ionizing radiation is categorized by the nature of the particles or electromagnetic waves that create the ionizing effect. These particles/waves have different ionization mechanisms, and may be grouped as:

• Directly ionizing. Charged particles (atomic nuclei, electrons, positrons, protons, muons, etc.) can ionize atoms directly by fundamental interaction through the Coulomb force if it carries sufficient kinetic energy. These particles must be moving at relativistic speeds to reach the required kinetic energy. Even photons (gamma rays and X-rays) can ionize atoms directly (despite they are electrically neutral) through the Photoelectric effect and the Compton effect, but secondary (indirect) ionization is much more significant.
  • Alpha radiation. Alpha radiation consist of alpha particles at high energy/speed. The production of alpha particles is termed alpha decay. Alpha particles consist of two protons and two neutrons bound together into a particle identical to a helium nucleus. Alpha particles are relatively large and carry a double positive charge. They are not very penetrating and a piece of paper can stop them. They travel only a few centimeters but deposit all their energies along their short paths.
  • Beta radiation. Beta radiation consist of free electrons or positrons at relativistic speeds. Beta particles (electrons) are much smaller than alpha particles. They carry a single negative charge. They are more penetrating than alpha particles, but thin aluminum metal can stop them. They can travel several meters but deposit less energy at any one point along their paths than alpha particles.
• Indirectly ionizing. Indirect ionizing radiation is electrically neutral particles and therefore does not interact strongly with matter. The bulk of the ionization effects are due to secondary ionizations.
  • Photon radiation (Gamma rays or X-rays). Photon radiation consist of high energy photons. These photons are particles/waves (Wave-Particle Duality) without rest mass or electrical charge. They can travel 10 meters or more in air. This is a long distance compared to alpha or beta particles. However, gamma rays deposit less energy along their paths. Lead, water, and concrete stop gamma radiation. Photons (gamma rays and X-rays) can ionize atoms directly through the Photoelectric effect and the Compton effect, where the relatively energetic electron is produced. The secondary electron will go on to produce multiple ionization events, therefore the secondary (indirect) ionization is much more significant.
  • Neutron radiation. Neutron radiation consist of free neutrons at any energies/speeds. Neutrons can be emitted by nuclear fission or by the decay of some radioactive atoms. Neutrons have zero electrical charge and cannot directly cause ionization. Neutrons ionize matter only indirectly. For example, when neutrons strike the hydrogen nuclei, proton radiation (fast protons) results. Neutrons can range from high speed, high energy particles to low speed, low energy particles (called thermal neutrons). Neutrons can travel hundreds of feet in air without any interaction.

Beta Radiation

Beta radiation consist of free electrons  or positrons at relativistic speeds. These particles are known as the beta particles. Beta particles are high-energy, high-speed electrons or positrons emitted by certain fission fragments or by certain primordial radioactive nuclei such as potassium-40. The beta particles are a form of ionizing radiation also known as beta rays. The production of beta particles is termed beta decay. There are two forms of beta decay, the electron decay (β− decay) and the positron decay (β+ decay). In a nuclear reactor occurs especially the β− decay, because the common feature of the fission products is an excess of neutrons (see Nuclear Stability). An unstable fission fragment with the excess of neutrons undergoes β− decay, where the neutron is converted into a proton, an electron, and an electron antineutrino.

Characteristics of Beta Radiation

Key characteristics of beta radiation are summarized in following points:

• Beta particles are energetic electrons, they are relatively light and carry a single negative charge.
• Their mass is equal to the mass of the orbital electrons with which they are interacting and unlike the alpha particle a much larger fraction of its kinetic energy can be lost in a single interaction.
• Their path is not so straightforward. The beta particles follow a very zig-zag path through absorbing material. This resulting path of particle is longer than the linear penetration (range) into the material.
• Since they have very low mass, beta particles reach mostly relativistic energies.
• Beta particles also differ from other heavy charged particles in the fraction of energy lost by radiative process known as the bremsstrahlung. Therefore for high energy beta radiation shielding dense materials are inappropriate.
• When the beta particle moves faster than the speed of light (phase velocity) in the material it generates a shock wave of electromagnetic radiation known as the Cherenkov radiation.
• The beta emission has the continuous spectrum.
• A 1 MeV beta particle can travel approximately 3.5 meters in air.
• Due to the presence of the bremsstrahlung low atomic number (Z) materials are appropriate as beta particle shields.

Radiation Protection Principles - Time, Distance, Shielding

In radiation protection there are three ways how to protect people from identified radiation sources:

• Limiting Time. The amount of radiation exposure depends directly (linearly) on the time people spend near the source of radiation. The dose can be reduced by limiting exposure time.
• Distance. The amount of radiation exposure depends on the distance from the source of radiation. Similarly to a heat from a fire, if you are too close, the intensity of heat radiation is high and you can get burned. If you are at the right distance, you can withstand there without any problems and moreover it is comfortable. If you are too far from heat source, the insufficiency of heat can also hurt you. This analogy, in a certain sense, can be applied to radiation also from radiation sources.
• Shielding. Finally, if the source is too intensive and time or distance do not provide sufficient radiation protection, the shielding must be used. Radiation shielding usually consist of barriers of lead, concrete or water. There are many many materials, which can be used for radiation shielding, but there are many many situations in radiation protection. It highly depends on the type of radiation to be shielded, its energy and many other parametres. For example, even depleted uranium can be used as a good protection from gamma radiation, but on the other hand uranium is absolutely inappropriate shielding of neutron radiation.

Shielding of Beta Radiation – Electrons

Beta radiation ionizes matter weaker than alpha radiation. On the other hand the ranges of beta particles are longer and depends strongly on initial kinetic energy of particle. Some have enough energy to be of concern regarding external exposure. A 1 MeV beta particle can travel approximately 3.5 meters in air. Such beta particles can penetrate into the body and deposit dose to internal structures near the surface. Therefore greater shielding than in case of alpha radiation is required.

Materials with low atomic number Z are appropriate as beta particle shields. With high Z materials the bremsstrahlung (secondary radiation – X-rays) is associated. This radiation is created during slowing down of beta particles while they travel in a very dense medium. Heavy clothing, thick cardboard or thin aluminium plate will provide protection from beta radiation and prevents of production of the bremsstrahlung.

See also more theory: Interaction of Beta Radiation with Matter

See also calculator: Beta activity to dose rate 

Shielding of Beta Radiation – Positrons

The coulomb forces that constitute the major mechanism of energy loss for electrons are present for either positive or negative charge on the particle and constitute the major mechanism of energy loss also for positrons. Whatever the interaction involves a repulsive or attractive force between the incident particle and orbital electron (or atomic nucleus), the impulse and energy transfer for particles of equal mass are about the same. Therefore positrons interact similarly with matter when they are energetic. The track of positrons in material is similar to the track of electrons. Even their specific energy loss and range are about the same for equal initial energies.

At the end of their path, positrons differ significantly from electrons. When a positron (antimatter particle) comes to rest, it interacts with an electron (matter particle), resulting in the annihilation of the both particles and the complete conversion of their rest mass to pure energy (according to the E=mc² formula) in the form of two oppositely directed 0.511 MeV gamma rays (photons).

Therefore any positron shield have to include also a gamma ray shield. In order to minimize the bremsstrahlung a multi-layered radiation shield is appropriate. Material for the first layer must fulfill the requirements for negative beta radiation shielding. First layer of such shield may be for example a thin aluminium plate (to shield positrons), while the second layer of such shield may be a dense material such as lead or depleted uranium.

See also: Shielding of Gamma Radiation

See also:

See also:

Radiation

See also:

Forms of Ionizing Radiation

Ionizing radiation is categorized by the nature of the particles or electromagnetic waves that create the ionizing effect. These particles/waves have different ionization mechanisms, and may be grouped as:

• Directly ionizing. Charged particles (atomic nuclei, electrons, positrons, protons, muons, etc.) can ionize atoms directly by fundamental interaction through the Coulomb force if it carries sufficient kinetic energy. These particles must be moving at relativistic speeds to reach the required kinetic energy. Even photons (gamma rays and X-rays) can ionize atoms directly (despite they are electrically neutral) through the Photoelectric effect and the Compton effect, but secondary (indirect) ionization is much more significant.
  • Alpha radiation. Alpha radiation consist of alpha particles at high energy/speed. The production of alpha particles is termed alpha decay. Alpha particles consist of two protons and two neutrons bound together into a particle identical to a helium nucleus. Alpha particles are relatively large and carry a double positive charge. They are not very penetrating and a piece of paper can stop them. They travel only a few centimeters but deposit all their energies along their short paths.
  • Beta radiation. Beta radiation consist of free electrons or positrons at relativistic speeds. Beta particles (electrons) are much smaller than alpha particles. They carry a single negative charge. They are more penetrating than alpha particles, but thin aluminum metal can stop them. They can travel several meters but deposit less energy at any one point along their paths than alpha particles.
• Indirectly ionizing. Indirect ionizing radiation is electrically neutral particles and therefore does not interact strongly with matter. The bulk of the ionization effects are due to secondary ionizations.
  • Photon radiation (Gamma rays or X-rays). Photon radiation consist of high energy photons. These photons are particles/waves (Wave-Particle Duality) without rest mass or electrical charge. They can travel 10 meters or more in air. This is a long distance compared to alpha or beta particles. However, gamma rays deposit less energy along their paths. Lead, water, and concrete stop gamma radiation. Photons (gamma rays and X-rays) can ionize atoms directly through the Photoelectric effect and the Compton effect, where the relatively energetic electron is produced. The secondary electron will go on to produce multiple ionization events, therefore the secondary (indirect) ionization is much more significant.
  • Neutron radiation. Neutron radiation consist of free neutrons at any energies/speeds. Neutrons can be emitted by nuclear fission or by the decay of some radioactive atoms. Neutrons have zero electrical charge and cannot directly cause ionization. Neutrons ionize matter only indirectly. For example, when neutrons strike the hydrogen nuclei, proton radiation (fast protons) results. Neutrons can range from high speed, high energy particles to low speed, low energy particles (called thermal neutrons). Neutrons can travel hundreds of feet in air without any interaction.

Alpha Radiation

Alpha radiation consist of alpha particles, that are energetic nuclei of helium. The production of alpha particles is termed alpha decay. Alpha particles consist of two protons and two neutrons bound together into a particle identical to a helium nucleus. Alpha particles are relatively large and carry a double positive charge.

Key characteristics of alpha particles are summarized in few following points:

• Alpha particles are energetic nuclei of helium and they are relatively heavy and carry a double positive charge.
• Typical alpha particle have kinetic energy about 5 MeV. This is due to the nature of alpha decay.
• Pure alpha decay is very rare, alpha decay is frequently accompanied by gamma radiation.
• Alpha particles interact with matter primarily through coulomb forces (ionization and excitation of matter) between their positive charge and the negative charge of the electrons from atomic orbitals.
• Alpha particles heavily ionize matter and they quickly lose their kinetic energy. Therefore alpha particles have very short ranges. On the other hand they deposit all their energies along their short paths.
• For example, the ranges of a 5 MeV alpha particle (most have such initial energy) are approximately only 0,002 cm in aluminium alloy or approximately 3.5 cm in air.
• The stopping power is well described by the Bethe formula.
• The Bragg curve is typical for alpha particles and for other heavy charged particles and describes energy loss of ionizing radiation during travel through matter.

See also: Interaction of Heavy Charged Particles with Matter

Shielding of Alpha Radiation

The shielding of alpha radiation alone does not pose a difficult problem. On the other hand alpha radioactive nuclides can lead to serious health hazards when they are ingested or inhaled (internal contamination). When they are ingested or inhaled, the alpha particles from their decay significantly harm the internal living tissue. Moreover pure alpha radiation is very rare, alpha decay is frequently accompanied by gamma radiation which shielding is another issue.

See also:

See also:

Radiation

See also:

Macroscopic Cross-section

The difference between the microscopic cross-section and macroscopic cross-section is very important and is restated for clarity. The microscopic cross section represents the effective target area of a single target nucleus for an incident particle. The units are given in barns or cm².

While the macroscopic cross-section represents the effective target area of all of the nuclei contained in the volume of the material. The units are given in cm^-1.

A macroscopic cross-section is derived from microscopic cross-section and the atomic number density:

Σ=σ.N

Here σ, which has units of m², is the microscopic cross-section. Since the units of N (nuclei density) are nuclei/m³, the macroscopic cross-section Σ have units of m^-1, thus in fact is an incorrect name, because it is not a correct unit of cross-sections. In terms of Σ_t (the total cross-section), the equation for the intensity of a neutron beam can be written as

-dI = N.σ.Σ_t.dx

Dividing this expression by I(x) gives

-dΙ(x)/I(x) = Σ_t.dx

Since dI(x) is the number of neutrons that collide in dx, the quantity –dΙ(x)/I(x) represents the probability that a neutron that has survived without colliding until x, will collide in the next layer dx. It follows that the probability P(x) that a neutron will travel a distance x without any interaction in the material, which is characterized by Σ_t, is:

P(x) = e^-Σ_t.x

From this equation, we can derive the probability that a neutron will make its first collision in dx. It will be the quantity P(x)dx. If the probability of the first collision in dx is independent of its past history, the required result will be equal to the probability that a neutron survives up to layer x without any interaction (~Σ_tdx) times the probability that the neutron will interact in the additional layer dx (i.e. ~e^-Σ_t.x).

P(x)dx = Σ_tdx . e^-Σ_t.x = Σ_t e^-Σ_t.x dx

Mean Free Path

From the equation for the probability of the first collision in dx we can calculate the mean free path that is traveled by a neutron between two collisions. This quantity is usually designated by the symbol λ and it is equal to the average value of x, the distance traveled by a neutron without any interaction, over the interaction probability distribution.

whereby one can distinguish λ_s, λ_a, λ_f, etc. This quantity is also known as the relaxation length, because it is the distance in which the intensity of the neutrons that have not caused a reaction has decreased with a factor e.

For materials with high absorption cross-section, the mean free path is very short and neutron absorption occurs mostly on the surface of the material. This surface absorption is called self-shielding because the outer layers of atoms shield the inner layers.

Macroscopic Cross-section of Mixtures and Molecules

Most materials are composed of several chemical elements and compounds. Most of chemical elements contains several isotopes of these elements (e.g. gadolinium with its six stable isotopes). For this reason most materials involve many cross-sections. Therefore, to include all the isotopes within a given material, it is necessary to determine the macroscopic cross section for each isotope and then sum all the individual macroscopic cross-sections.

In this section both factors (different atomic densities and different cross-sections) will be considered in the calculation of the macroscopic cross-section of mixtures.

First, consider the Avogadro’s number N₀ = 6.022 x 10²³, is the number of particles (molecules, atoms) that is contained in the amount of substance given by one mole. Thus if M is the molecular weight, the ratio N₀/M equals to the number of molecules in 1g of the mixture. The number of molecules per cm³ in the material of density ρ and the macroscopic cross-section for mixtures are given by following equations:

N_i = ρ_i.N₀ / M_i

Note that, in some cases, the cross-section of the molecule is not equal to the sum of cross-sections of its individual nuclei. For example the cross-section of neutron elastic scattering of water exhibits anomalies for thermal neutrons. It occurs, because the kinetic energy of an incident neutron is of the order or less than the chemical binding energy and therefore the scattering of slow neutrons by water (H₂O) is greater than by free nuclei (2H + O).

See also:

See also:

Neutron Cross-section

See also: