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Rhodium and Palladium – Comparison – Properties

This article contains comparison of key thermal and atomic properties of rhodium and palladium, two comparable chemical elements from the periodic table. It also contains basic descriptions and applications of both elements. Rhodium vs Palladium.

rhodium and palladium - comparison

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Rhodium and Palladium – About Elements

Rhodium

Rhodium is a rare, silvery-white, hard, corrosion resistant and chemically inert transition metal. It is a noble metal and a member of the platinum group.

Palladium

Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as the platinum group metals (PGMs). These have similar chemical properties, but palladium has the lowest melting point and is the least dense of them. More than half the supply of palladium and its congener platinum is used in catalytic converters.

Rhodium in Periodic Table

Palladium in Periodic Table

Source: www.luciteria.com

Rhodium and Palladium – Applications

Rhodium

The element’s major use (approximately 80% of world rhodium production) is as one of the catalysts in the three-way catalytic converters in automobiles. Because rhodium metal is inert against corrosion and most aggressive chemicals, and because of its rarity, rhodium is usually alloyed with platinum or palladium and applied in high-temperature and corrosion-resistive coatings. In nuclear reactors, rhodium-based detectors are often used for incore neutron flux measuring.

Palladium

More than half the supply of palladium and its congener platinum is used in catalytic converters, which convert as much as 90% of the harmful gases in automobile exhaust into less noxious substances. Palladium is also used in electronics, dentistry, medicine, hydrogen purification, chemical applications, groundwater treatment, and jewelry. Palladium-based alloys are being extensively used in fuel cell technology applications. The metal is also employed in historic photographic printing process. Palladium has been used as a precious metal in jewelry since 1939 as an alternative to platinum in the alloys called “white gold”.

Rhodium and Palladium – Comparison in Table

Element Rhodium Palladium
Density 12.45 g/cm3 12.023 g/cm3
Ultimate Tensile Strength 950 MPa 135 MPa
Yield Strength N/A 30 MPa
Young’s Modulus of Elasticity 380 GPa 121 GPa
Mohs Scale 6 4.8
Brinell Hardness 1100 MPa 320 MPa
Vickers Hardness 1246 MPa 400 MPa
Melting Point 1964 °C 1554.9 °C
Boiling Point 3695 °C 2963 °C
Thermal Conductivity 150 W/mK 72 W/mK
Thermal Expansion Coefficient 8.2 µm/mK 11.8 µm/mK
Specific Heat 0.242 J/g K 0.24 J/g K
Heat of Fusion 21.5 kJ/mol 17.6 kJ/mol
Heat of Vaporization 493 kJ/mol 357 kJ/mol