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Zirconium and Uranium – Comparison – Properties

This article contains comparison of key thermal and atomic properties of zirconium and uranium, two comparable chemical elements from the periodic table. It also contains basic descriptions and applications of both elements. Zirconium vs Uranium.

zirconium and uranium - comparison

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Zirconium and Uranium – About Elements

Zirconium

Zirconium is a lustrous, grey-white, strong transition metal that resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Zirconium is widely used as a cladding for nuclear reactor fuels. The desired properties of these alloys are a low neutron-capture cross-section and resistance to corrosion under normal service conditions.

Uranium

Uranium is a silvery-white metal in the actinide series of the periodic table. Uranium is weakly radioactive because all isotopes of uranium are unstable, with half-lives varying between 159,200 years and 4.5 billion years. Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead, and slightly lower than that of gold or tungsten. Uranium is commonly found at low levels (a few ppm – parts per million) in all rocks, soil, water, plants, and animals (including humans). Uranium occurs also in seawater, and can be recovered from the ocean water. Significant concentrations of uranium occur in some substances such as uraninite (the most common uranium ore), phosphate rock deposits, and other minerals.

Zirconium in Periodic Table

Uranium in Periodic Table

Source: www.luciteria.com

Zirconium and Uranium – Applications

Zirconium

Most zircon is used directly in high-temperature applications. This material is refractory, hard, and resistant to chemical attack. Because of these properties, zircon finds many applications, few of which are highly publicized. Its main use is as an opacifier, conferring a white, opaque appearance to ceramic materials. Zirconium and its alloys are widely used as a cladding for nuclear reactor fuels. Zirconium alloyed with niobium or tin has excellent corrosion properties. The high corrosion resistance of zirconium alloys results from the natural formation of a dense stable oxide on the surface of the metal. This film is self healing, it continues to grow slowly at temperatures up to approximately 550 °C (1020 °F), and it remains tightly adherent. The desired property of these alloys is also a low neutron-capture cross-section. The disadvantages of zirconium are low strength properties and low heat resistance, which can be eliminated, for example, by alloying with niobium.

Uranium

The main use of uranium in the civilian sector is to fuel nuclear power plants. One kilogram of uranium-235 can theoretically produce about 20 terajoules of energy, assuming complete fission; as much energy as 1.5 million kilograms (1,500 tonnes) of coal. Typical reactor may contain about 100 tonnes of enriched uranium (i.e. about 113 tonnes of uranium dioxide). This fuel is loaded within, for example, 157 fuel assemblies composed of over 45,000 fuel rods. A common fuel assembly contain energy for approximately 4 years of operation at full power. The removed fuel (spent nuclear fuel) still contains about 96% of reusable material (it must be removed due to decreasing kinf of an assembly). Before (and, occasionally, after) the discovery of radioactivity, uranium was primarily used in small amounts for yellow glass and pottery glazes, such as uranium glass. Uranium is also used by the military to power nuclear submarines and in nuclear weapons. Due to its high density, this material is found in inertial guidance systems and in gyroscopic compasses.[10] Depleted uranium is preferred over similarly dense metals due to its ability to be easily machined and cast as well as its relatively low cost. The main risk of exposure to depleted uranium is chemical poisoning by uranium oxide rather than radioactivity (uranium being only a weak alpha emitter). Depleted uranium is uranium that has much less uranium-235 than natural uranium. It is considerably less radioactive than natural uranium. It is a dense metal that can be used as ballast for ships and counterweights for aircraft. It is also used in ammunition and armour. Depleted uranium can be also used to shield radiation. Depleted uranium is much more effective due to its higher Z. Depleted uranium is used for shielding in portable gamma ray sources. Uranium is used in high-speed steels as an alloying agent to improve strength and toughness. Uranium trioxide (also called uranic oxide) with formula UO3, is an orange-yellow powder and is used as a pigment for ceramics. In glasses it produces a beautiful greenish-yellow “uranium glass”.

Zirconium and Uranium – Comparison in Table

Element Zirconium Uranium
Density 6.511 g/cm3 19.05 g/cm3
Ultimate Tensile Strength 330 MPa 390 MPa
Yield Strength 230 MPa 190 MPa
Young’s Modulus of Elasticity 88 GPa 208 GPa
Mohs Scale 5 6
Brinell Hardness 650 MPa 2400 MPa
Vickers Hardness 900 MPa 1960 MPa
Melting Point 1855 °C 1132 °C
Boiling Point 4377 °C 4131 °C
Thermal Conductivity 22.7 W/mK 27 W/mK
Thermal Expansion Coefficient 5.7 µm/mK 13.9 µm/mK
Specific Heat 0.27 J/g K 0.12 J/g K
Heat of Fusion 16.9 kJ/mol 8.52 kJ/mol
Heat of Vaporization 591 kJ/mol 417 kJ/mol