## About Polypropylene

Polypropylene have properties that are similar to polyethylene, but it is slightly harder and more heat resistant. It is a white, mechanically rugged material and has a high chemical resistance. Polypropylene is recyclable and has the number “5” as its resin identification code.

### Summary

Name | Polypropylene |

Phase at STP | solid |

Density | 900 kg/m3 |

Ultimate Tensile Strength | 27 MPa |

Yield Strength | N/A |

Young’s Modulus of Elasticity | 1.3 GPa |

Brinell Hardness | 50 BHN |

Melting Point | 337 °C |

Thermal Conductivity | 0.2 W/mK |

Heat Capacity | 1700 J/g K |

Price | 1.1 $/kg |

## Density of Polypropylene

In words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is **kilograms per cubic meter** (**kg/m ^{3}**). The Standard English unit is

**pounds mass per cubic foot**(

**lbm/ft**).

^{3}Density of Polypropylene is **900 kg/m ^{3}.**

### Example: Density

Calculate the height of a cube made of Polypropylene, which weighs one metric ton.

**Solution:**

**Density** is defined as the **mass per unit volume**. It is mathematically defined as mass divided by volume: **ρ = m/V**

As the volume of a cube is the third power of its sides (V = a^{3}), the height of this cube can be calculated:

The height of this cube is then **a = 1.036 m**.

### Density of Materials

## Mechanical Properties of Polypropylene

### Strength of Polypropylene

In mechanics of materials, the **strength of a material** is its ability to withstand an applied load without failure or plastic deformation. **Strength of materials** basically considers the relationship between the **external loads** applied to a material and the resulting **deformation** or change in material dimensions. In designing structures and machines, it is important to consider these factors, in order that the material selected will have adequate strength to resist applied loads or forces and retain its original shape.

**Strength of a material** is its ability to withstand this applied load without failure or plastic deformation. For tensile stress, the capacity of a material or structure to withstand loads tending to elongate is known as ultimate tensile strength (UTS). Yield strength or yield stress is the material property defined as the stress at which a material begins to deform plastically whereas yield point is the point where nonlinear (elastic + plastic) deformation begins. In case of tensional stress of a uniform bar (stress-strain curve), the **Hooke’s law** describes behaviour of a bar in the elastic region. The Young’s modulus of elasticity is the elastic modulus for tensile and compressive stress in the linear elasticity regime of a uniaxial deformation and is usually assessed by tensile tests.

See also: Strength of Materials

### Ultimate Tensile Strength of Polypropylene

Ultimate tensile strength of Polypropylene is 27 MPa.

### Yield Strength of Polypropylene

Yield strength of Polypropylene** **is N/A.

### Modulus of Elasticity of Polypropylene

The Young’s modulus of elasticity of Polypropylene is 1.3 MPa.

### Hardness of Polypropylene

In materials science, **hardness** is the ability to withstand **surface indentation** (**localized plastic deformation**) and **scratching**. **Brinell hardness test** is one of indentation hardness tests, that has been developed for hardness testing. In Brinell tests, a hard, **spherical indenter** is forced under a specific load into the surface of the metal to be tested.

The **Brinell hardness number** (HB) is the load divided by the surface area of the indentation. The diameter of the impression is measured with a microscope with a superimposed scale. The Brinell hardness number is computed from the equation:

Brinell hardness of Polypropylene is approximately 50 BHN (converted).

See also: Hardness of Materials

### Example: Strength

Assume a plastic rod, which is made of Polypropylene. This plastic rod has a cross-sectional area of 1 cm^{2}. Calculate the tensile force needed to achieve the ultimate tensile strength for this material, which is: UTS = 27 MPa.

Solution:

**Stress (σ)** can be equated to the load per unit area or the force (F) applied per cross-sectional area (A) perpendicular to the force as:

therefore, the tensile force needed to achieve the ultimate tensile strength is:

**F** = UTS x A = 27 x 10^{6} x 0.0001 = **2 700 N**

## Thermal Properties of Polypropylene

### Polypropylene – Melting Point

**Melting point of Polypropylene is 337 ****°C**.

Note that, these points are associated with the standard atmospheric pressure. In general, **melting** is a **phase change** of a substance from the solid to the liquid phase. The **melting point** of a substance is the temperature at which this phase change occurs. The **melting point **also defines a condition in which the solid and liquid can exist in equilibrium. For various chemical compounds and alloys, it is difficult to define the melting point, since they are usually a mixture of various chemical elements.

### Polypropylene – Thermal Conductivity

Thermal conductivity of **Polypropylene** is **0.2** **W/(m·K)**.

The heat transfer characteristics of a solid material are measured by a property called the **thermal conductivity**, k (or λ), measured in **W/m.K**. It is a measure of a substance’s ability to transfer heat through a material by conduction. Note that **Fourier’s law** applies for all matter, regardless of its state (solid, liquid, or gas), therefore, it is also defined for liquids and gases.

The **thermal conductivity** of most liquids and solids varies with temperature. For vapors, it also depends upon pressure. In general:

Most materials are very nearly homogeneous, therefore we can usually write ** k = k (T)**. Similar definitions are associated with thermal conductivities in the y- and z-directions (ky, kz), but for an isotropic material the thermal conductivity is independent of the direction of transfer, kx = ky = kz = k.

### Polypropylene – Specific Heat

**Specific heat of Polypropylene is ****1700 J/g K**.

**Specific heat, or specific heat capacity, **is a property related to** internal energy** that is very important in thermodynamics. The **intensive properties c_{v}** and

**are defined for pure, simple compressible substances as partial derivatives of the**

*c*_{p}**internal energy**and

*u(T, v)***enthalpy**, respectively:

*h(T, p)*where the subscripts **v** and **p** denote the variables held fixed during differentiation. The properties **c _{v} **and

**c**are referred to as

_{p}**specific heats**(or

**heat capacities**) because under certain special conditions they relate the temperature change of a system to the amount of energy added by heat transfer. Their SI units are

**J/kg K**or

**J/mol K**.

### Example: Heat transfer calculation

Thermal conductivity is defined as the amount of heat (in watts) transferred through a square area of material of given thickness (in metres) due to a difference in temperature. The lower the thermal conductivity of the material the greater the material’s ability to resist heat transfer.

Calculate the rate of __heat flux__ through a wall 3 m x 10 m in area (A = 30 m^{2}). The wall is 15 cm thick (L_{1}) and it is made of Polypropylene with the __thermal conductivity__ of k_{1} = 0.2 W/m.K (poor thermal insulator). Assume that, the indoor and the outdoor __temperatures__ are 22°C and -8°C, and the __convection heat transfer coefficients__ on the inner and the outer sides are h_{1} = 10 W/m^{2}K and h_{2} = 30 W/m^{2}K, respectively. Note that, these convection coefficients strongly depend especially on ambient and interior conditions (wind, humidity, etc.).

Calculate the heat flux (**heat loss**) through this wall.

**Solution:**

As was written, many of the heat transfer processes involve composite systems and even involve a combination of both __conduction__ and __convection__. With these composite systems, it is often convenient to work with an__ overall heat transfer coefficient__**, **known as a **U-factor**. The U-factor is defined by an expression analogous to **Newton’s law of cooling**:

The **overall heat transfer coefficient** is related to the total thermal resistance and depends on the geometry of the problem.

Assuming one-dimensional heat transfer through the plane wall and disregarding radiation, the **overall heat transfer coefficient** can be calculated as:

The **overall heat transfer coefficient **is then: U = 1 / (1/10 + 0.15/0.2 + 1/30) = 1.13 W/m^{2}K

The heat flux can be then calculated simply as: q = 1.13 [W/m^{2}K] x 30 [K] = 33.96 W/m^{2}

The total heat loss through this wall will be: **q _{loss} **= q . A = 33.96 [W/m

^{2}] x 30 [m

^{2}] =

**1018.87 W**