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Titanium and Zirconium – Comparison – Properties

This article contains comparison of key thermal and atomic properties of titanium and zirconium, two comparable chemical elements from the periodic table. It also contains basic descriptions and applications of both elements. Titanium vs Zirconium.

titanium and zirconium - comparison

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Titanium and Zirconium – About Elements

Titanium

Titanium is a lustrous transition metal with a silver color, low density, and high strength. Titanium is resistant to corrosion in sea water, aqua regia, and chlorine. Titanium can be used in surface condensers. These condensers use tubes that are usually made of stainless steel, copper alloys, or titanium depending on several selection criteria (such as thermal conductivity or corrosion resistance). Titanium condenser tubes are usually the best technical choice, however titanium is very expensive material and the use of titanium condenser tubes is associated with very high initial costs.

Zirconium

Zirconium is a lustrous, grey-white, strong transition metal that resembles hafnium and, to a lesser extent, titanium. Zirconium is mainly used as a refractory and opacifier, although small amounts are used as an alloying agent for its strong resistance to corrosion. Zirconium is widely used as a cladding for nuclear reactor fuels. The desired properties of these alloys are a low neutron-capture cross-section and resistance to corrosion under normal service conditions.

Titanium in Periodic Table

Zirconium in Periodic Table

Source: www.luciteria.com

Titanium and Zirconium – Applications

Titanium

The two most useful properties of the metal are corrosion resistance and strength-to-density ratio, the highest of any metallic element. The corrosion resistance of titanium alloys at normal temperatures is unusually high. These properties determine application of titanium and its alloys. The earliest production application of titanium was in 1952, for the nacelles and firewalls of the Douglas DC-7 airliner. High specific strength, good fatigue resistance and creep life, and good fracture toughness are characteristics that make titanium a preferred metal for aerospace applications. Aerospace applications, including use in both structural (airframe) components and jet engines, still account for the largest share of titanium alloy use. On the supersonic aircraft SR-71, titanium was used for 85% of the structure. Due to very high inertness, titanium has many biomedical applications, which is based on its inertness in the human body, that is, resistance to corrosion by body fluids.

Zirconium

Most zircon is used directly in high-temperature applications. This material is refractory, hard, and resistant to chemical attack. Because of these properties, zircon finds many applications, few of which are highly publicized. Its main use is as an opacifier, conferring a white, opaque appearance to ceramic materials. Zirconium and its alloys are widely used as a cladding for nuclear reactor fuels. Zirconium alloyed with niobium or tin has excellent corrosion properties. The high corrosion resistance of zirconium alloys results from the natural formation of a dense stable oxide on the surface of the metal. This film is self healing, it continues to grow slowly at temperatures up to approximately 550 °C (1020 °F), and it remains tightly adherent. The desired property of these alloys is also a low neutron-capture cross-section. The disadvantages of zirconium are low strength properties and low heat resistance, which can be eliminated, for example, by alloying with niobium.

Titanium and Zirconium – Comparison in Table

Element Titanium Zirconium
Density 4.507 g/cm3 6.511 g/cm3
Ultimate Tensile Strength 434 MPa, 293 MPa (pure) 330 MPa
Yield Strength 380 MPa 230 MPa
Young’s Modulus of Elasticity 116 GPa 88 GPa
Mohs Scale 6 5
Brinell Hardness 700 – 2700 MPa 650 MPa
Vickers Hardness 800 – 3400 MPa 900 MPa
Melting Point 1668 °C 1855 °C
Boiling Point 3287 °C 4377 °C
Thermal Conductivity 21.9 W/mK 22.7 W/mK
Thermal Expansion Coefficient 8.6 µm/mK 5.7 µm/mK
Specific Heat 0.52 J/g K 0.27 J/g K
Heat of Fusion 15.45 kJ/mol 16.9 kJ/mol
Heat of Vaporization 421 kJ/mol 591 kJ/mol