Neptunium metal is silvery and tarnishes when exposed to air. Neptunium is the first transuranic element.
Protons and Neutrons in Neptunium
Neptunium is a chemical element with atomic number 93 which means there are 93 protons in its nucleus. Total number of protons in the nucleus is called the atomic number of the atom and is given the symbol Z. The total electrical charge of the nucleus is therefore +Ze, where e (elementary charge) equals to 1,602 x 10-19 coulombs.
The total number of neutrons in the nucleus of an atom is called the neutron number of the atom and is given the symbol N. Neutron number plus atomic number equals atomic mass number: N+Z=A. The difference between the neutron number and the atomic number is known as the neutron excess: D = N – Z = A – 2Z.
For stable elements, there is usually a variety of stable isotopes. Isotopes are nuclides that have the same atomic number and are therefore the same element, but differ in the number of neutrons. Mass numbers of typical isotopes of Neptunium are 237.
Main Isotopes of Neptunium
Neptunium occurs in 2 natural isotopes: 237Np and 239Np and both occur only in traces.
Neptunium-237 is composed of 93 protons, 144 neutrons, and 93 electrons.
Neptunium-239 is composed of 93 protons, 146 neutrons, and 93 electrons.
Electrons and Electron Configuration
The number of electrons in an electrically-neutral atom is the same as the number of protons in the nucleus. Therefore, the number of electrons in neutral atom of Neptunium is 93. Each electron is influenced by the electric fields produced by the positive nuclear charge and the other (Z – 1) negative electrons in the atom.
Since the number of electrons and their arrangement are responsible for the chemical behavior of atoms, the atomic number identifies the various chemical elements. The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element’s electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. In the periodic table, the elements are listed in order of increasing atomic number Z.
Electron configuration of Neptunium is [Rn] 5f4 6d1 7s2.
Possible oxidation states are +3,4,5,6.
|Number of protons
|Number of neutrons (typical isotopes)
|Number of electrons
|[Rn] 5f4 6d1 7s2