Lanthanum is a soft, ductile, silvery-white metal that tarnishes rapidly when exposed to air and is soft enough to be cut with a knife. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. It is also sometimes considered the first element of the 6th-period transition metals and is traditionally counted among the rare earth elements.
|Element category||Rare Earth Metal|
|Phase at STP||Solid|
|Ultimate Tensile Strength||130 MPa|
|Yield Strength||125 MPa|
|Young’s Modulus of Elasticity||36.6 GPa|
|Brinell Hardness||350 MPa|
|Vickers Hardness||360 MPa|
|Melting Point||920 °C|
|Boiling Point||3454 °C|
|Thermal Conductivity||13 W/mK|
|Thermal Expansion Coefficient||12.1 µm/mK|
|Specific Heat||0.19 J/g K|
|Heat of Fusion||6.2 kJ/mol|
|Heat of Vaporization||414 kJ/mol|
|Electrical resistivity [nanoOhm meter]||615|
|Magnetic Susceptibility||+118.6e-6 cm^3/mol|
Applications of Lanthanum
Lanthanum is not extensively used metal. However, its alloys have a variety of interesting uses. A lanthanum-nickel alloy is used to store hydrogen gas for use in hydrogen-powered vehicles. Lanthanum is also found in the anode of nickel metal hydride batteries (NiMH) used in hybrid cars. Lanthanum is an important component of mischmetal alloy. A typical composition includes approximately 55% cerium, 25% lanthanum, and 15-18% neodymium with other rare earth metals following. The best-known use for this alloy is in ‘flints’ for cigarette lighters.
Production and Price of Lanthanum
Raw materials prices change daily. They are primarily driven by supply, demand and energy prices. In 2019, prices of pure Lanthanum were at around 640 $/kg.
The ores containing lanthanum, such as monazite, are typically contain a range of other rare earths. Consequently they undergo a series of chemical treatments to remove rare earths such as thorium and cerium to yield lanthanum salts. Monazite is an important ore for thorium, lanthanum, and cerium. It is often found in placer deposits. India, Madagascar, and South Africa have large deposits of monazite sands. The deposits in India are particularly rich in monazite.
Mechanical Properties of Lanthanum
Strength of Lanthanum
In mechanics of materials, the strength of a material is its ability to withstand an applied load without failure or plastic deformation. Strength of materials basically considers the relationship between the external loads applied to a material and the resulting deformation or change in material dimensions. In designing structures and machines, it is important to consider these factors, in order that the material selected will have adequate strength to resist applied loads or forces and retain its original shape. Strength of a material is its ability to withstand this applied load without failure or plastic deformation.
For tensile stress, the capacity of a material or structure to withstand loads tending to elongate is known as ultimate tensile strength (UTS). Yield strength or yield stress is the material property defined as the stress at which a material begins to deform plastically whereas yield point is the point where nonlinear (elastic + plastic) deformation begins.
See also: Strength of Materials
Ultimate Tensile Strength of Lanthanum
Ultimate tensile strength of Lanthanum is 130 MPa.
Yield Strength of Lanthanum
Yield strength of Lanthanum is 125 MPa.
Modulus of Elasticity of Lanthanum
The Young’s modulus of elasticity of Lanthanum is 125 MPa.
Hardness of Lanthanum
In materials science, hardness is the ability to withstand surface indentation (localized plastic deformation) and scratching. Brinell hardness test is one of indentation hardness tests, that has been developed for hardness testing. In Brinell tests, a hard, spherical indenter is forced under a specific load into the surface of the metal to be tested.
Brinell hardness of Lanthanum is approximately 350 MPa.
The Vickers hardness test method was developed by Robert L. Smith and George E. Sandland at Vickers Ltd as an alternative to the Brinell method to measure the hardness of materials. The Vickers hardness test method can be also used as a microhardness test method, which is mostly used for small parts, thin sections, or case depth work.
Vickers hardness of Lanthanum is approximately 360 MPa.
Scratch hardness is the measure of how resistant a sample is to permanent plastic deformation due to friction from a sharp object. The most common scale for this qualitative test is Mohs scale, which is used in mineralogy. The Mohs scale of mineral hardness is based on the ability of one natural sample of mineral to scratch another mineral visibly.
Lanthanum is has a hardness of approximately 2.5.
See also: Hardness of Materials
Lanthanum – Crystal Structure
A possible crystal structure of Lanthanum is double hexagonal close-packed structure.
In metals, and in many other solids, the atoms are arranged in regular arrays called crystals. A crystal lattice is a repeating pattern of mathematical points that extends throughout space. The forces of chemical bonding causes this repetition. It is this repeated pattern which control properties like strength, ductility, density, conductivity (property of conducting or transmitting heat, electricity, etc.), and shape. There are 14 general types of such patterns known as Bravais lattices.
See also: Crystal Structure of Materials
Crystal Structure of Lanthanum
Thermal Properties of Lanthanum
Lanthanum – Melting Point and Boiling Point
Melting point of Lanthanum is 920°C.
Boiling point of Lanthanum is 3454°C.
Note that, these points are associated with the standard atmospheric pressure.
Lanthanum – Thermal Conductivity
Thermal conductivity of Lanthanum is 13 W/(m·K).
The heat transfer characteristics of a solid material are measured by a property called the thermal conductivity, k (or λ), measured in W/m.K. It is a measure of a substance’s ability to transfer heat through a material by conduction. Note that Fourier’s law applies for all matter, regardless of its state (solid, liquid, or gas), therefore, it is also defined for liquids and gases.
Coefficient of Thermal Expansion of Lanthanum
Linear thermal expansion coefficient of Lanthanum is 12.1 µm/(m·K)
Thermal expansion is generally the tendency of matter to change its dimensions in response to a change in temperature. It is usually expressed as a fractional change in length or volume per unit temperature change.
Lanthanum – Specific Heat, Latent Heat of Fusion, Latent Heat of Vaporization
Specific heat of Lanthanum is 0.19 J/g K.
Heat capacity is an extensive property of matter, meaning it is proportional to the size of the system. Heat capacity C has the unit of energy per degree or energy per kelvin. When expressing the same phenomenon as an intensive property, the heat capacity is divided by the amount of substance, mass, or volume, thus the quantity is independent of the size or extent of the sample.
Latent Heat of Fusion of Lanthanum is 6.2 kJ/mol.
Latent Heat of Vaporization of Lanthanum is 414 kJ/mol.
Latent heat is the amount of heat added to or removed from a substance to produce a change in phase. This energy breaks down the intermolecular attractive forces, and also must provide the energy necessary to expand the gas (the pΔV work). When latent heat is added, no temperature change occurs. The enthalpy of vaporization is a function of the pressure at which that transformation takes place.
Lanthanum – Electrical Resistivity – Magnetic Susceptibility
Electrical property refers to the response of a material to an applied electric field. One of the principal characteristics of materials is their ability (or lack of ability) to conduct electrical current. Indeed, materials are classified by this property, that is, they are divided into conductors, semiconductors, and nonconductors.
See also: Electrical Properties
Magnetic property refers to the response of a material to an applied magnetic field. The macroscopic magnetic properties of a material are a consequence of interactions between an external magnetic field and the magnetic dipole moments of the constituent atoms. Different materials react to the application of magnetic field differently.
See also: Magnetic Properties
Electrical Resistivity of Lanthanum
Electrical resistivity of Lanthanum is 615 nΩ⋅m.
Electrical conductivity and its converse, electrical resistivity, is a fundamental property of a material that quantifies how Lanthanum conducts the flow of electric current. Electrical conductivity or specific conductance is the reciprocal of electrical resistivity.
Magnetic Susceptibility of Lanthanum
Magnetic susceptibility of Lanthanum is +118.6e-6 cm^3/mol.
In electromagnetism, magnetic susceptibility is the measure of the magnetization of a substance. Magnetic susceptibility is a dimensionless proportionality factor that indicates the degree of magnetization of Lanthanum in response to an applied magnetic field.
Application and prices of other elements